(b) Quinine in a 3.925-g antimalarial tablet was dissolved in sufficient 0.10 M HCI to give 1.000 L. Dilution of a 20.00 mL aliquot to 100.00 mL yielded a solution that gave a reading of 415 at 347.5 nm. A second 20.00 mL aliquot was mixed with 10.0 mL of 50-ppm quinine solution before dilution to 100 mL. The fluorescence intensity of this solution was 503. Calculate the percentage of quinine in the tablet.

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter14: Applications Of Ultraviolet-visible Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 14.10QAP: The acid-base indicator HIn undergoes the following reaction in dilute aqueous solution:...
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(b)
Quinine in a 3.925-g antimalarial tablet was dissolved in sufficient 0.10 M HCI to
give 1.000 L. Dilution of a 20.00 mL aliquot to 100.00 mL yielded a solution that
gave a reading of 415 at 347.5 nm. A second 20.00 mL aliquot was mixed with 10.0
mL of 50-ppm quinine solution before dilution to 100 mL. The fluorescence intensity
of this solution was 503. Calculate the percentage of quinine in the tablet.
Transcribed Image Text:(b) Quinine in a 3.925-g antimalarial tablet was dissolved in sufficient 0.10 M HCI to give 1.000 L. Dilution of a 20.00 mL aliquot to 100.00 mL yielded a solution that gave a reading of 415 at 347.5 nm. A second 20.00 mL aliquot was mixed with 10.0 mL of 50-ppm quinine solution before dilution to 100 mL. The fluorescence intensity of this solution was 503. Calculate the percentage of quinine in the tablet.
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