At equilibrium, the concentrations in this system were found to be [N₂] = [0₂] = 0.100 M and [NO] N₂(g) + O₂(g) = 2 NO(g) If more NO is added, bringing its concentration to 0.900 M, what will the final concentration of NO be after equilibrium is re-established? = 0.600 M.

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At equilibrium, the concentrations in this system were found to be [N2]=[O2]=0.100 M and [NO]=0.600 M.

N2(g) + O2(g)↽−−⇀ 2NO(g)

If more NO is added, bringing its concentration to 0.900 M, what will the final concentration of NO be after equilibrium is re‑established?

### Understanding Chemical Equilibrium: A Case Study

**Problem Statement:**

At equilibrium, the concentrations in the following system were found to be \([N_2] = [O_2] = 0.100 \, \text{M}\) and \([NO] = 0.600 \, \text{M}\).

\[ \mathrm{N_2(g) + O_2(g) \rightleftharpoons 2NO(g)} \]

If additional NO is added, bringing its concentration to \(0.900 \, \text{M}\), what will be the final concentration of NO after equilibrium is re-established?

### Step-by-Step Solution:

1. **Initial Equilibrium Status:**
   At the initial equilibrium, the following concentrations are given:
   - \([N_2] = 0.100 \, \text{M}\)
   - \([O_2] = 0.100 \, \text{M}\)
   - \([NO] = 0.600 \, \text{M}\)

   Using the equilibrium expression for the reaction:
   
   \[ \mathrm{K_c = \frac{[NO]^2}{[N_2][O_2]}} \]

2. **Calculate the Equilibrium Constant (\(K_c\)):**
   
   Substitute the given equilibrium concentrations into the equilibrium expression:
   
   \[ \mathrm{K_c = \frac{(0.600)^2}{(0.100)(0.100)} = \frac{0.360}{0.010} = 36} \]

3. **Disturbance by Adding NO:**
   When more NO is added to the system, bringing its concentration to \(0.900 \, \text{M}\):
   
   New initial concentration of NO: \([NO]_{\text{initial}} = 0.900 \, \text{M}\)

4. **Re-establishing Equilibrium:**
   
   Let's assume that \( \, x \, \text{M} \) of NO reacts to re-establish the equilibrium concentration.
   
   The change in concentrations will be:
   - NO decreases by \(2x\)
   - \(N_2\) increases by \(x\)
   - \(O_2\) increases by \(x\)
   
   Therefore, at the new equilibrium:
Transcribed Image Text:### Understanding Chemical Equilibrium: A Case Study **Problem Statement:** At equilibrium, the concentrations in the following system were found to be \([N_2] = [O_2] = 0.100 \, \text{M}\) and \([NO] = 0.600 \, \text{M}\). \[ \mathrm{N_2(g) + O_2(g) \rightleftharpoons 2NO(g)} \] If additional NO is added, bringing its concentration to \(0.900 \, \text{M}\), what will be the final concentration of NO after equilibrium is re-established? ### Step-by-Step Solution: 1. **Initial Equilibrium Status:** At the initial equilibrium, the following concentrations are given: - \([N_2] = 0.100 \, \text{M}\) - \([O_2] = 0.100 \, \text{M}\) - \([NO] = 0.600 \, \text{M}\) Using the equilibrium expression for the reaction: \[ \mathrm{K_c = \frac{[NO]^2}{[N_2][O_2]}} \] 2. **Calculate the Equilibrium Constant (\(K_c\)):** Substitute the given equilibrium concentrations into the equilibrium expression: \[ \mathrm{K_c = \frac{(0.600)^2}{(0.100)(0.100)} = \frac{0.360}{0.010} = 36} \] 3. **Disturbance by Adding NO:** When more NO is added to the system, bringing its concentration to \(0.900 \, \text{M}\): New initial concentration of NO: \([NO]_{\text{initial}} = 0.900 \, \text{M}\) 4. **Re-establishing Equilibrium:** Let's assume that \( \, x \, \text{M} \) of NO reacts to re-establish the equilibrium concentration. The change in concentrations will be: - NO decreases by \(2x\) - \(N_2\) increases by \(x\) - \(O_2\) increases by \(x\) Therefore, at the new equilibrium:
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