A student determines the concentration chloride in an unknown sample by pipetting 10 mL of the sample and 10 mL of 1.000 x 10-5 M quinine solution to a 100 mL flask and diluting to volume with 1 M H₂SO4. A series of six chloride standards were prepared using a 0.0100 M standard chloride solution, adding an increasing volume of chloride to 100 mL volumetric flasks, in addition to 10 mL of 1.000 x 10-5 M quinine. Each solution was diluted to volume with 1 M H₂SO4. Calculate the chloride concentration (mM) for the unknown using the collected fluorescence data and the Stern-Volmer graph below for the data. Chloride Fluorescence 0 Molarity Intensity 0.000000 140.00 0.001000 137.70 0.002000 134.70 0.003000 131.30 0.004000 127.61 0.005000 123.70 Unknown 133.50
A student determines the concentration chloride in an unknown sample by pipetting 10 mL of the sample and 10 mL of 1.000 x 10-5 M quinine solution to a 100 mL flask and diluting to volume with 1 M H₂SO4. A series of six chloride standards were prepared using a 0.0100 M standard chloride solution, adding an increasing volume of chloride to 100 mL volumetric flasks, in addition to 10 mL of 1.000 x 10-5 M quinine. Each solution was diluted to volume with 1 M H₂SO4. Calculate the chloride concentration (mM) for the unknown using the collected fluorescence data and the Stern-Volmer graph below for the data. Chloride Fluorescence 0 Molarity Intensity 0.000000 140.00 0.001000 137.70 0.002000 134.70 0.003000 131.30 0.004000 127.61 0.005000 123.70 Unknown 133.50
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:A student determines the
concentration chloride in an
unknown sample by pipetting 10 mL
of the sample and 10 mL of 1.000 x
10-5 M quinine solution to a 100 mL
flask and diluting to volume with 1
M H₂SO4. A series of six chloride
standards were prepared using a
0.0100 M standard chloride solution,
adding an increasing volume of
chloride to 100 mL volumetric flasks,
in addition to 10 mL of 1.000 × 10-5
M quinine. Each solution was diluted
to volume with 1 M H₂SO4.
Calculate the chloride concentration
(mm) for the unknown using the
collected fluorescence data and the
Stern-Volmer graph below for the
data.
Chloride Fluorescence D
Molarity Intensity
0.000000 140.00
0.001000 137.70
0.002000 134.70
0.003000 131.30
0.004000 127.61
0.005000 123.70
Unknown 133.50
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