A solution is prepared by mixing 4.55 g of carbon disulfide (CS2) and an unknown mass of acetone (CH3COCH3) at a temperature of 35.0\deg C. The total vapor pressure of the solution is 446 torr. If the pure vapor pressures of carbon disulfide and acetone at 35.0 \deg C are 515 torr and 332 torr, respectively, what mass of acetone (in grams) was used to create the solution. Do not place units in the answer blank. The molar mass of carbon disulfide is 76.14 g/ mol, and the molar mass of acetone is 58.08 g/mol.

A solution is prepared by mixing 4.55 g of carbon disulfide (CS2) and an unknown mass of acetone (CH3COCH3) at a temperature of 35.0\deg C. The total vapor pressure of the solution is 446 torr. If the pure vapor pressures of carbon disulfide and acetone at 35.0 \deg C are 515 torr and 332 torr, respectively, what mass of acetone (in grams) was used to create the solution. Do not place units in the answer blank. The molar mass of carbon disulfide is 76.14 g/ mol, and the molar mass of acetone is 58.08 g/mol.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter11: Properties Of Solutions

Section: Chapter Questions

Problem 67E: Which of the following will have the lowest total vapor pressure at 25C? a. pure water (vapor...

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Calculate the freezing point of 525 g of water that contains 25.0 g of NaCl. Assume i, the vant Hoff factor, is 1.85 for NaCl.
A forensic chemist is given a white solid that is suspected of being pure cocaine (C17H21NO4, molar mass = 303.35 g/mol). She dissolves 1.22 0.01 g of the solid in 15.60 0.01 g benzene. The freezing point is lowered by 1.32 0.04C. a. What is the molar mass of the substance? Assuming that the percent uncertainty in the calculated molar mass is the same as the percent uncertainty in the temperature change, calculate the uncertainty in the molar mass. b. Could the chemist unequivocally state that the substance is cocaine? For example, is the uncertainty small enough to distinguish cocaine from codeine (C18H21NO3, molar mass = 299.36 g/mol)? c. Assuming that the absolute uncertainties in the measurements of temperature and mass remain unchanged, how could the chemist improve the precision of her results?
1. Vapor pressure: Arrange the following aqueous solutions in order of increasing vapor pressure at 25°C: 0.35 m C2H4(OH)2 (ethylene glycol, nonvolatile solute); 0.50 m sugar; 0.20 m KBr; and 0.20 m Na2SO4. C2H4(OH)2 < sugar < KBr < Na2SO4 Na2SO4 < sugar < KBr < C2H4(OH)2 sugar < C2H4(OH)2 < KBr < Na2SO4 KBr < sugar < Na2SO4 < C2H4(OH)2
Juice (d=1.0g/mL) from freshly harvested grapes has about 24% sucrose by mass. What is the molality of sucrose, C12H22O11, in the grape juice after 25% (by mass) of the water content has been removed? Assume a volume of 15.0 L.
Which of the following will have the lowest total vapor pressure at 25C? a. pure water (vapor pressure = 23.8 torr at 25C) b. a solution of glucose in water with C6H12O6=0.01 c. a solution of sodium chloride in water with NaCl = 0.01 d. a solution of methanol in water with CH3OH=0.2 (Consider the vapor pressure of both methanol [143 torr at 25C] and water.)
To make homemade ice cream, you cool the milk and cream by immersing the container in ice and a concentrated solution of rock salt (NaCl) in water. If you want to have a water-salt solution that freezes at 10. C, what mass of NaCl must you add to 3.0 kg of water? (Assume the vant Hoff factor, i, for NaCl is 1.85.)
The solubility of NaCl in water at 100 C is 39.1 g/100. g of water Calculate the boiling point of this solution. (Assume i = 1.85 for NaCl.)
a. Use the following data to calculate the enthalpy of hydration for calcium chloride and calcium iodide. Lattice Energy Hsoln CaCl2(s) 2247kj/mol 46kj/mol Cal2(s) 2059kj/mol 104kj/mol b. Based on your answers to part a, which ion, Cl or I, is more strongly attracted to water?
Consider two hypothetical pure substances, AB(s) and XY(s). When equal molar amounts of these substances are placed in separate 500-mL samples of water, they undergo the following reactions: AB(s)A+(aq)+B(aq)XY(s)XY(aq) a Which solution would you expect to have the lower boiling point? Why? b Would you expect the vapor pressures of the two solutions to be equal? If not, which one would you expect to have the higher vapor pressure? c Describe a procedure that would make the two solutions have the same boiling point. d If you took 250 mL of the AB(aq) solution prepared above, would it have the same boiling point as the original solution? Be sure to explain your answer. e The container of XY(aq) is left out on the bench top for several days, which allows some of the water to evaporate from the solution. How would the melting point of this solution compare to the melting point of the original solution?
A 1.00 mol/kg aqueous sulfuric acid solution, H2SO4,freezes at 4.04 C. Calculate i, the vant Hoff factor,for sulfuric acid in this solution.
A compound contains 42.9% C, 2.4% H, 16.6% N, and 38.1% O. The addition of 3.16 g of this compound to 75.0 mL of cyclohexane (d=0.779g/mL) gives a solution with a freezing point at 0.0C. Using Table 10.2, determine the molecular formula of the compound.

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