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Organic Chemistry

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution

Section16.SE: Something Extra

Problem 70AP

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Additional book problems addressing this skill: Ch. 15: 31-38, 42-44
Ch. 16: Skill 1 Provide the mechanism, reagents, and products for the
following EAS reactions: halogenation, nitration, sulfonation, alkylation
and acetylation
A. Problem 16-33: Triphenylmethane can be prepared by reaction of benzene and chloroform
in the presence of AlCl3. Propose a mechanism for this reaction:
(
H<
+
CHCl3
CH-CI₂
CHelz
AlCl3
+ Alcl 3
C-
HIC

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