а Relative Transmittance 0.8 0.6 INFRARED SPECTRUM 3000 wwwp 2000 Wavenumber (cm-1) (https://webbook.nist.gov/chemistry) 1000 NIST Chemistry WebBook 1- For the above shown IR-Spectrum (Indicate the structure of the organic molecule). What are the characteristic peaks present?
In the IR spectra we can distinctly see the following peaks i.e at 3050cm-1, 1600cm-1, 900cm-1, 730cm-1.
The IR peak at 3050cm-1 may appear for aromatic C-H stretching. The range of aromatic C-H stretching frequency lies in between 3000-3100cm-1. Peak for no other functional group falls in this region.
A sharp but weak peak is also observed at 1600cm-1 from which we can say the presence of C=C functionality. As C=C stretching frequency appears in the region of 1600-1680cm-1. Hence the compound is aromatic but C=C stretching frequency is very weak. The compound may have very low resonance energy compared to benzene.
The peaks at 900 and 730cm-1 arise due to aromatic bending. (In plane and out of plane C-H bending appear at 900cm-1 and 730cm-1 respectively).
No other characteristic peaks are observed. So it is clear from the above data that this a aromatic hydrocarbon.
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