а Relative Transmittance 0.8 0.6 INFRARED SPECTRUM 3000 wwwp 2000 Wavenumber (cm-1) (https://webbook.nist.gov/chemistry) 1000 NIST Chemistry WebBook 1- For the above shown IR-Spectrum (Indicate the structure of the organic molecule). What are the characteristic peaks present?

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**Anthracene Infrared Spectrum Analysis**

**Graph Explanation:**
The image shows the infrared (IR) spectrum of anthracene. The x-axis represents the wavenumber in cm⁻¹, ranging from 4000 to 500, while the y-axis represents the relative transmittance.

**Key Features:**
- The spectrum exhibits several sharp peaks, indicating vibrational transitions.
- Major peaks can be observed around 3050 cm⁻¹ and between 700-900 cm⁻¹, which are characteristic of aromatic C-H stretching and bending vibrations, respectively.

**Tasks:**
1. **Interpretation of the IR Spectrum:**
   - Identify the structure of the organic molecule using the IR spectrum.
   - Determine the characteristic peaks present in the spectrum.

2. **IR, NMR, and Mass Spectra for Methyl Ethyl Ester:**
   - Draw the IR, NMR, and mass spectra for methyl ethyl ester.

3. **IR, NMR, and Mass Spectra for Acetyl Salicylic Acid (Aspirin):**
   - Draw the IR, NMR, and mass spectra for acetyl salicylic acid, commonly known as aspirin.

For further details, refer to the NIST Chemistry WebBook: [NIST Chemistry WebBook](https://webbook.nist.gov/chemistry/).
Transcribed Image Text:**Anthracene Infrared Spectrum Analysis** **Graph Explanation:** The image shows the infrared (IR) spectrum of anthracene. The x-axis represents the wavenumber in cm⁻¹, ranging from 4000 to 500, while the y-axis represents the relative transmittance. **Key Features:** - The spectrum exhibits several sharp peaks, indicating vibrational transitions. - Major peaks can be observed around 3050 cm⁻¹ and between 700-900 cm⁻¹, which are characteristic of aromatic C-H stretching and bending vibrations, respectively. **Tasks:** 1. **Interpretation of the IR Spectrum:** - Identify the structure of the organic molecule using the IR spectrum. - Determine the characteristic peaks present in the spectrum. 2. **IR, NMR, and Mass Spectra for Methyl Ethyl Ester:** - Draw the IR, NMR, and mass spectra for methyl ethyl ester. 3. **IR, NMR, and Mass Spectra for Acetyl Salicylic Acid (Aspirin):** - Draw the IR, NMR, and mass spectra for acetyl salicylic acid, commonly known as aspirin. For further details, refer to the NIST Chemistry WebBook: [NIST Chemistry WebBook](https://webbook.nist.gov/chemistry/).
Expert Solution
Step 1

In the IR spectra we can distinctly see the following peaks i.e at 3050cm-1, 1600cm-1, 900cm-1, 730cm-1.

The IR peak at 3050cm-1 may appear for aromatic C-H stretching. The range of aromatic C-H stretching frequency lies in between 3000-3100cm-1. Peak for no other functional group falls in this region.

 

A sharp but weak peak is also observed at 1600cm-1 from which we can say the presence of C=C functionality. As C=C stretching frequency appears in the region of 1600-1680cm-1. Hence the compound is aromatic but C=C stretching frequency is very weak. The compound may have very low resonance energy compared to benzene.

 

The peaks at 900 and 730cm-1 arise due to aromatic bending. (In plane and out of plane C-H bending appear at 900cm-1 and 730cm-1 respectively).

 

No other characteristic peaks are observed. So it is clear from the above data that this a aromatic hydrocarbon.

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