i.MS: M+ is not seen but equals 144.Relative IntensityIR:12010080ني د ن نB.27 2920 20 30013037383300E.4030005060C. Shift = 1.3 ppm, 4H, doublet of doubletD. Shift = 1.9 ppm, 1H, multipletShift = 3.9 ppm, 1H, broad.707275-1700Some wavenumbers are marked for clarity.Proton NMR: Note: J's not provided because of the complex splitting.A. Shift =0.8 ppm, 12H, doubletShift = 1.1 ppm, 2H, multiplet77 79 818283840080m/z9010011112110Iwww1201227130What is the numerical value of the base peak in the MS shown above?What is the minimum number of H present in the molecule? How do you know?What functional group(s) besides alkyl is/are present? Use other spectra to help.What is the likely molecular formula for the compoundDraw a structure for the compound consistent with the information collected from the spectra.140143

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Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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i.
MS: M+ is not seen but equals 144.
Relative Intensity
IR:
120
100
80
ني د ن ن
B.
27 29
20 20 3001
30
3738
3300
E.
40
3000
50
60
C. Shift = 1.3 ppm, 4H, doublet of doublet
D. Shift = 1.9 ppm, 1H, multiplet
Shift = 3.9 ppm, 1H, broad.
70
7275
-
1700
Some wavenumbers are marked for clarity.
Proton NMR: Note: J's not provided because of the complex splitting.
A. Shift =0.8 ppm, 12H, doublet
Shift = 1.1 ppm, 2H, multiplet
77 79 8182838400
80
m/z
90
100
11112
110
I
www
120
1227
130
What is the numerical value of the base peak in the MS shown above?
What is the minimum number of H present in the molecule? How do you know?
What functional group(s) besides alkyl is/are present? Use other spectra to help.
What is the likely molecular formula for the compound
Draw a structure for the compound consistent with the information collected from the spectra.
140
143

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