a) Consider the sparingly soluble salt lead(II) sulfate. Write a balanced chemical equation showing the dissolution of lead(II) sulfate. b) Given the following information, provide the net reaction for the spontaneous reaction and determine the cell potential under standard conditions that would occur from these two half-reactions: Pb2"(aq) + 2e- → Pb(s) E°red = -0.1262 V PbSO4(s) + 2e- → Pb(s) + SO4² (aq) E°red = –0.3505 V c) Calculate the equilibrium constant at 283 K (10.° C) for the spontaneous redox reaction you wrote in part b.

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a) Consider the sparingly soluble salt lead(II) sulfate. Write a balanced chemical equation
showing the dissolution of lead(II) sulfate.
b) Given the following information, provide the net reaction for the spontaneous reaction
and determine the cell potential under standard conditions that would occur from these
two half-reactions:
Pb2"(aq) + 2e-
→ Pb(s)
E°red = –0.1262 V
PBSO4(s) + 2e-
→ Pb(s) + SO4²'(aq)
E°red = -0.3505 V
c) Calculate the equilibrium constant at 283 K (10.° C) for the spontaneous redox reaction
you wrote in part b.
d) Using only the information provided in this problem, calculate the solubility product
constant of lead(II) sulfate at 10. °C.
e) Is the dissolution of lead(II) sulfate at 10. °C thermodynamically favorable? Justify your
response by determining AG°rxn at 10. °C, using only the information provided or
determined in this problem.
Transcribed Image Text:a) Consider the sparingly soluble salt lead(II) sulfate. Write a balanced chemical equation showing the dissolution of lead(II) sulfate. b) Given the following information, provide the net reaction for the spontaneous reaction and determine the cell potential under standard conditions that would occur from these two half-reactions: Pb2"(aq) + 2e- → Pb(s) E°red = –0.1262 V PBSO4(s) + 2e- → Pb(s) + SO4²'(aq) E°red = -0.3505 V c) Calculate the equilibrium constant at 283 K (10.° C) for the spontaneous redox reaction you wrote in part b. d) Using only the information provided in this problem, calculate the solubility product constant of lead(II) sulfate at 10. °C. e) Is the dissolution of lead(II) sulfate at 10. °C thermodynamically favorable? Justify your response by determining AG°rxn at 10. °C, using only the information provided or determined in this problem.
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