a Consider the hypothetical reaction B → E +F which is assumed to occur by the mechanism k1 B +B 2 B* +B k1 B* 3 E+ F where B* represents a B molecule with enough energy to surmount the reaction energy barrier. Derive the rate law for the production of E using the steady-state approximation. d[F] k1 B] + k, Rate dt kį k2 [B]? ki k2 [B][E] k1 [F] + k, [B] d[E] Rate dt kı k2 [B]? k1 B] + k2 d[B] Rate dt d[E] kįk2 [B]? k1 B] + k2 Rate dt
a Consider the hypothetical reaction B → E +F which is assumed to occur by the mechanism k1 B +B 2 B* +B k1 B* 3 E+ F where B* represents a B molecule with enough energy to surmount the reaction energy barrier. Derive the rate law for the production of E using the steady-state approximation. d[F] k1 B] + k, Rate dt kį k2 [B]? ki k2 [B][E] k1 [F] + k, [B] d[E] Rate dt kı k2 [B]? k1 B] + k2 d[B] Rate dt d[E] kįk2 [B]? k1 B] + k2 Rate dt
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![a Consider the hypothetical reaction
B → E +F
which is assumed to occur by the mechanism
k1
B +B 2 B* +B
k1
B* 3 E+ F
where B* represents a B molecule with enough energy to surmount the reaction energy barrier.
Derive the rate law for the production of E using the steady-state approximation.
d[F]
k1 B] + k,
Rate
dt
kį k2 [B]?
ki k2 [B][E]
k1 [F] + k, [B]
d[E]
Rate
dt
kı k2 [B]?
k1 B] + k2
d[B]
Rate
dt
d[E]
kįk2 [B]?
k1 B] + k2
Rate
dt](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb417ffb6-eb7d-4466-b664-89f966a306a6%2Ff832f112-b0ff-49bd-8798-48dd9d9c3724%2F629wssc.png&w=3840&q=75)
Transcribed Image Text:a Consider the hypothetical reaction
B → E +F
which is assumed to occur by the mechanism
k1
B +B 2 B* +B
k1
B* 3 E+ F
where B* represents a B molecule with enough energy to surmount the reaction energy barrier.
Derive the rate law for the production of E using the steady-state approximation.
d[F]
k1 B] + k,
Rate
dt
kį k2 [B]?
ki k2 [B][E]
k1 [F] + k, [B]
d[E]
Rate
dt
kı k2 [B]?
k1 B] + k2
d[B]
Rate
dt
d[E]
kįk2 [B]?
k1 B] + k2
Rate
dt
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