a Consider the hypothetical reaction B → E +F which is assumed to occur by the mechanism k1 B +B 2 B* +B k1 B* 3 E+ F where B* represents a B molecule with enough energy to surmount the reaction energy barrier. Derive the rate law for the production of E using the steady-state approximation. d[F] k1 B] + k, Rate dt kį k2 [B]? ki k2 [B][E] k1 [F] + k, [B] d[E] Rate dt kı k2 [B]? k1 B] + k2 d[B] Rate dt d[E] kįk2 [B]? k1 B] + k2 Rate dt

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Chapter1: Chemical Foundations
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a Consider the hypothetical reaction
B → E +F
which is assumed to occur by the mechanism
k1
B +B 2 B* +B
k1
B* 3 E+ F
where B* represents a B molecule with enough energy to surmount the reaction energy barrier.
Derive the rate law for the production of E using the steady-state approximation.
d[F]
k1 B] + k,
Rate
dt
kį k2 [B]?
ki k2 [B][E]
k1 [F] + k, [B]
d[E]
Rate
dt
kı k2 [B]?
k1 B] + k2
d[B]
Rate
dt
d[E]
kįk2 [B]?
k1 B] + k2
Rate
dt
Transcribed Image Text:a Consider the hypothetical reaction B → E +F which is assumed to occur by the mechanism k1 B +B 2 B* +B k1 B* 3 E+ F where B* represents a B molecule with enough energy to surmount the reaction energy barrier. Derive the rate law for the production of E using the steady-state approximation. d[F] k1 B] + k, Rate dt kį k2 [B]? ki k2 [B][E] k1 [F] + k, [B] d[E] Rate dt kı k2 [B]? k1 B] + k2 d[B] Rate dt d[E] kįk2 [B]? k1 B] + k2 Rate dt
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