A certain half-reaction has a standard reduction potential Ed=-0.06 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that must provide at least 0.70 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the anode of the cell. Data Ag* (aq) + e → Ag (s) Al3+ (aq) + 3e- → Al (s) 0.7996 Is there a minimum standard reduction potential that the half-reaction used at the cathode of this cell can have? O yes, there is a minimum. = v -1.676 Au+ (aq) + e-- Au (s) 1.692 If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. Au3+ (aq) + 3e Au (s) 1.498 O no minimum Ba2+ (aq) + 2e Ba (s) -2.912 Br2 (1) + 2e- + 2Br (aq) 1.066 Ca2+ (aq) + 2e - Ca (s) -2.868 Is there a maximum standard reduction potential that the half-reaction used at the cathode of this cell can have? E red = Iv Cl2 (g) + 2e → 2CI- (aq) 1.35827 O yes, there is a maximum. Co2+ (aq) + 2e → Co (s) -0.28 If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. Co3+ (aq) + e- → Co2+ (aq) Cr2+ (aq) + 2e - Cr (s) Cr3+ (ag) + 3e → Cr (s) 1.92 O no maximum -0.913 -0.744 Cr3+ (aq) + e- - Cr2+ (aq) --0.407 Cro42- (aq) + 4H20 (1) + 3e + Cr(OH)3 (s) + 50H- (aq) -0.13 By using the information in the ALEKS Data tab, write a balanced equation describing a half reaction that could be used at the cathode of this cell. Cu2+ (aq) + 2e- Cu (s) 0.3419 Cu2+ (ag) + e- + Cut (aq) 0.153 Cu+ (aq) + e-- Cu (s) 0.521 Note: write the half reaction as it would actually occur at the cathode. 2.866 F2 (g) + 2e - 2F" (aq) Fe2+ (aq) + 2e-- Fe (s) -0.447 Fe3+ (ag) + e-- Fe2+ (ag) 0.771 Explanation Check Fe3+ (ag) + 3e- Fe (s) -0.037 MacBook Air

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Data
2H+ (aq) + 2e H2 (g)
0.000
2H20 (1) + 2e → H2 (g) + 20H (aq)
-0.8277
H202 (aq) + 2H+ (aq) + 2e 2H20 (1)
1.776
I2 (s) + 2e 21 (aq)
0.5355
2103 (aq) + 12H+ (aq) + 10e → I2 (s) + 6H20 (I)
1.195
Mg2+ (aq) + 2e Mg (s)
-2.372
Mn2+ (ag) + 2e Mn (s)
-1.185
MnO2 (s) + 4H+ (aq) + 2e Mn2+ (aq) + 2H20 ()
1.224
Mn04 (aq) + 8H+ (aq) † 5e →
Mn2+ (aq) + 4H20 (1)
1.507
MnO4 (aq) + 2H20 (1) + 3e- MnO2 (s) + 40H (aq)
0.595
HNO2 (aq) + H+ (aq) + e¯ → NO (g) + H2O (I)
0.983
N2 (g) + 4H2O (1) + 4e¯ → 4OH (aq) + N2H4 (aq)
-1.16
NO3 (aq) + 4H+ (aq) + 3e → NO (g) + 2H20 (1)
0.957
Na+ (aq) + e → Na (s)
-2.71
Ni2+ (aq) + 2e Ni (s)
-0.257
02 (g) + 4H+ (aq) + 4e¯ → 2H20 (I)
1.229
02 (g) + 2H2O (1) + 4e¯ → 40H (aq)
0.401
O2 (g) + 2H+ (aq) + 2e¯ → H202 (aq)
0.695
Pb2+ (aq) + 2e Pb (s)
-0.1262
PbSO4 (s) + H+ (aq) + 2e¯ - Pb (s) + HSO4 (aq)
-0.3588
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Transcribed Image Text:Data 2H+ (aq) + 2e H2 (g) 0.000 2H20 (1) + 2e → H2 (g) + 20H (aq) -0.8277 H202 (aq) + 2H+ (aq) + 2e 2H20 (1) 1.776 I2 (s) + 2e 21 (aq) 0.5355 2103 (aq) + 12H+ (aq) + 10e → I2 (s) + 6H20 (I) 1.195 Mg2+ (aq) + 2e Mg (s) -2.372 Mn2+ (ag) + 2e Mn (s) -1.185 MnO2 (s) + 4H+ (aq) + 2e Mn2+ (aq) + 2H20 () 1.224 Mn04 (aq) + 8H+ (aq) † 5e → Mn2+ (aq) + 4H20 (1) 1.507 MnO4 (aq) + 2H20 (1) + 3e- MnO2 (s) + 40H (aq) 0.595 HNO2 (aq) + H+ (aq) + e¯ → NO (g) + H2O (I) 0.983 N2 (g) + 4H2O (1) + 4e¯ → 4OH (aq) + N2H4 (aq) -1.16 NO3 (aq) + 4H+ (aq) + 3e → NO (g) + 2H20 (1) 0.957 Na+ (aq) + e → Na (s) -2.71 Ni2+ (aq) + 2e Ni (s) -0.257 02 (g) + 4H+ (aq) + 4e¯ → 2H20 (I) 1.229 02 (g) + 2H2O (1) + 4e¯ → 40H (aq) 0.401 O2 (g) + 2H+ (aq) + 2e¯ → H202 (aq) 0.695 Pb2+ (aq) + 2e Pb (s) -0.1262 PbSO4 (s) + H+ (aq) + 2e¯ - Pb (s) + HSO4 (aq) -0.3588 CBook Air II F8 F7 F9 F10 F1 F12 + 9 delete
A certain half-reaction has a standard reduction potential Ed=-0.06 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that must
provide at least 0.70 V of electrical power. The cell will operate under standard conditions.
Note for advanced students: assume the engineer requires this half-reaction to happen at the anode of the cell.
Data
Ag* (aq) + e- → Ag (s)
0.7996
Is there a minimum standard reduction
potential that the half-reaction used at
the cathode of this cell can have?
O yes, there is a minimum.
E
red
A13+ (aq) + 3e- → Al (s)
%3D
-1.676
Au+ (aq) + e - Au (s)
1.692
If so, check the "yes" box and calculate
the minimum. Round your answer to 2
decimal places. If there is no lower
limit, check the "no" box.
Au3+ (aq) + 3e Au (s)
1.498
O no minimum
Ba2+ (aq) + 2e Ba (s)
-2.912
Br2 (1) + 2e-
2Br (aq)
1.066
Ca2+ (aq) + 2e- - Ca (s)
-2.868
Is there a maximum standard reduction
potential that the half-reaction used at
the cathode of this cell can have?
= Iv
Cl2 (g) + 2e → 2C1- (aq)
1.35827
O yes, there is a maximum.
%3D
red
Co2+ (aq) + 2e- → Co (s)
Co3+ (aq) + e- → Co2+ (aq)
Cr2+ (aq) + 2e Cr (s)
-0.28
If so, check the "yes" box and calculate
the maximum. Round your answer to 2
decimal places. If there is no upper
limit, check the "no" box.
1.92
-0.913
O no maximum
Cr3+ (ag) + 3e -
Cr (s)
-0.744
Cr3+ (aq) + e- Cr2+ (aq)
Cro42- (aq) + 4H20 (I) + 3e- + Cr(OH)3 (s) + 50H¯ (aq)
Cu2+ (aq) + 2e + Cu (s)
-0.407
--0.13
By using the information in the ALEKS
Data tab, write a balanced equation
describing a half reaction that could be
used at the cathode of this cell.
0.3419
Cu2+ (ag) + e- + Cut (aq)
0.153
Cu+ (aq) + e-- Cu (s)
0.521
Note: write the half reaction as it would
actually occur at the cathode.
2.866
F2 (g) + 2e
Fe2+ (aq) + 2e-- Fe (s)
→ 2F" (aq)
-0.447
Fe3+ (aq) + e- - Fe2+ (aq)
Fe3+ (aq) + 3e- Fe (s)
0.771
Explanation
Check
-0.037
MacBook Air
F12
F11
吕0
F9
F10
esc
D00 F4
F7
F8
F6
F5
Transcribed Image Text:A certain half-reaction has a standard reduction potential Ed=-0.06 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that must provide at least 0.70 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the anode of the cell. Data Ag* (aq) + e- → Ag (s) 0.7996 Is there a minimum standard reduction potential that the half-reaction used at the cathode of this cell can have? O yes, there is a minimum. E red A13+ (aq) + 3e- → Al (s) %3D -1.676 Au+ (aq) + e - Au (s) 1.692 If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. Au3+ (aq) + 3e Au (s) 1.498 O no minimum Ba2+ (aq) + 2e Ba (s) -2.912 Br2 (1) + 2e- 2Br (aq) 1.066 Ca2+ (aq) + 2e- - Ca (s) -2.868 Is there a maximum standard reduction potential that the half-reaction used at the cathode of this cell can have? = Iv Cl2 (g) + 2e → 2C1- (aq) 1.35827 O yes, there is a maximum. %3D red Co2+ (aq) + 2e- → Co (s) Co3+ (aq) + e- → Co2+ (aq) Cr2+ (aq) + 2e Cr (s) -0.28 If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. 1.92 -0.913 O no maximum Cr3+ (ag) + 3e - Cr (s) -0.744 Cr3+ (aq) + e- Cr2+ (aq) Cro42- (aq) + 4H20 (I) + 3e- + Cr(OH)3 (s) + 50H¯ (aq) Cu2+ (aq) + 2e + Cu (s) -0.407 --0.13 By using the information in the ALEKS Data tab, write a balanced equation describing a half reaction that could be used at the cathode of this cell. 0.3419 Cu2+ (ag) + e- + Cut (aq) 0.153 Cu+ (aq) + e-- Cu (s) 0.521 Note: write the half reaction as it would actually occur at the cathode. 2.866 F2 (g) + 2e Fe2+ (aq) + 2e-- Fe (s) → 2F" (aq) -0.447 Fe3+ (aq) + e- - Fe2+ (aq) Fe3+ (aq) + 3e- Fe (s) 0.771 Explanation Check -0.037 MacBook Air F12 F11 吕0 F9 F10 esc D00 F4 F7 F8 F6 F5
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