A certain half-reaction has a standard reduction potential E=+0.21 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that must provide at least 1.30 V of electrical power. The cell will operate under standard conditions. nla Data Note for advanced students: assume the engineer requires this half-reaction to happen at t Half-Reaction E° (V) Ag+ (aq) + e → Ag (s) Al3+ (aq) + 3e-- Al (s) 0.7996 -1.676 Is there a minimum standard reduction potential that the half-reaction used at the cathode of this cell can have? yes, there is a minimum. E = Ov red Au+ (aq) + e - Au (s) 1.692 Au3+ (aq) + 3e - Au (s) Ba2+ (aq) + 2e - Ba (s) 1.498 If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. -2.912 O no minimum Br2 (1) + 2e- + 2Br (aq) 1.066 Ca2+ (aq) + 2e- - Ca (s) -2.868 Cl2 (9) + 2e- 2CI- (aq) 1.35827 Is there a maximum standard reduction potential that the half-reaction used at the cathode of this cell can have? = Ov red O yes, there is a maximum. Co2+ (aq) + 2e-- Co (s) -0.28 !! Co3+ (aq) + e- - Co2+ (aq) 1.92 If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. Cr2+ (aq) + 2e- Cr (s) Cr3+ (ag) + 3e Cr (s) -0.913 O no maximum -0.744 Cr+ (aq) + e- - Cr2+ (aq) --0.407 Cro42- (aq) + 4H20 (1) + 3e - Cr(OH)3 (s) + 50H (aq) -0.13 Cu2+ (aq) + 2e - Cu (s) 0.3419 By using the information in the ALEKS Data tab, write a balanced equation describing a half reaction that could be used at the cathode of this cell. Cu2+ (aq) + e Cut (aq) Cut (aq) + e - Cu (s) 0.153 0.521 Note: write the half reaction as it would F2 (9) + 2e - 2F (aq) 2.866 actually occur at the cathode. Fe2+ (aq) + 2e - Fe (s) -0.447 Fe+ (aq) + e - Fe2+ (aq) 0.771
A certain half-reaction has a standard reduction potential E=+0.21 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that must provide at least 1.30 V of electrical power. The cell will operate under standard conditions. nla Data Note for advanced students: assume the engineer requires this half-reaction to happen at t Half-Reaction E° (V) Ag+ (aq) + e → Ag (s) Al3+ (aq) + 3e-- Al (s) 0.7996 -1.676 Is there a minimum standard reduction potential that the half-reaction used at the cathode of this cell can have? yes, there is a minimum. E = Ov red Au+ (aq) + e - Au (s) 1.692 Au3+ (aq) + 3e - Au (s) Ba2+ (aq) + 2e - Ba (s) 1.498 If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. -2.912 O no minimum Br2 (1) + 2e- + 2Br (aq) 1.066 Ca2+ (aq) + 2e- - Ca (s) -2.868 Cl2 (9) + 2e- 2CI- (aq) 1.35827 Is there a maximum standard reduction potential that the half-reaction used at the cathode of this cell can have? = Ov red O yes, there is a maximum. Co2+ (aq) + 2e-- Co (s) -0.28 !! Co3+ (aq) + e- - Co2+ (aq) 1.92 If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. Cr2+ (aq) + 2e- Cr (s) Cr3+ (ag) + 3e Cr (s) -0.913 O no maximum -0.744 Cr+ (aq) + e- - Cr2+ (aq) --0.407 Cro42- (aq) + 4H20 (1) + 3e - Cr(OH)3 (s) + 50H (aq) -0.13 Cu2+ (aq) + 2e - Cu (s) 0.3419 By using the information in the ALEKS Data tab, write a balanced equation describing a half reaction that could be used at the cathode of this cell. Cu2+ (aq) + e Cut (aq) Cut (aq) + e - Cu (s) 0.153 0.521 Note: write the half reaction as it would F2 (9) + 2e - 2F (aq) 2.866 actually occur at the cathode. Fe2+ (aq) + 2e - Fe (s) -0.447 Fe+ (aq) + e - Fe2+ (aq) 0.771
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:2H+ (aq) + 2e + H2 (g)
0.000
2H20 (1) + 2e - H2 (g) + 20H (aq)
-0.8277
H2O2 (aq) + 2H+ (aq) + 2e¯ → 2H20 (1)
1.776
12 (s) + 2e 21- (aq)
0.5355
2103 (aq) + 12H (aq) + 10e I2 (s) + 6H20 (I)
1.195
A Mg2+ (aq) + 2e Mg (s)
-2.372
Mn2+ (aq) + 2e Mn (s)
-1.185
1.224
MnO2 (s) + 4H+ (aq) + 2e- Mn2+ (aq) + 2H20 (I)
1.507
MnO4 (aq) + 8H+ (aq) + 5e Mn2+ (aq) + 4H20 (I)
0.595
Mn04 (aq) + 2H20 (1) + 3e MnO2 (s) + 40H (aq)
0.983
HNO2 (aq) + H+ (aq) + e- → NO (g) + H20 (1)
-1.16
N2 (g) + 4H2O (1) + 4e¯ → 40H (aq) + N2H4 (aq)
0.957
NO3 (aq) + 4H+ (aq) + 3e → NO (g) + 2H20 (I)
-2.71
Na+ (aq) + e Na (s)
-0.257
Ni2+ (ag) + 2e Ni (s)
1.229
O2 (g) + 4H+ (aq) + 4e → 2H2O (I)
0.401
O2 (g) + 2H20 (I) + 4e¯ -→ 40H¯ (aq)
0.695
O2 (g) + 2H+ (aq) + 2e¯ → H2O2 (aq)
-0.1262
Pb2+ (aq) + 2e → Pb (s)
-0.3588
PbSO4 (s) + Ht (aq) + 2e → Pb (s) + HSO4 (aq)
0.172
HSO4 (aq) + 3H+ (aq) + 2e H2SO3 (aq) + H2O (1)
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Transcribed Image Text:A certain half-reaction has a standard reduction potential E=+0.21 V. An engineer proposes using this half-reaction at the anode of a galvanic cell that must
provide at least 1.30 V of electrical power. The cell will operate under standard conditions. l Data
Note for advanced students: assume the engineer requires this half-reaction to happen at t
Half-Reaction
E° (V)
Ag+ (aq) + e + Ag (s)
A13+ (aq) + 3e - Al (s)
Au+ (aq) + e - Au (s)
Au3+ (aq) + 3e - Au (s)
0.7996
-1.676
Is there a minimum standard reduction
potential that the half-reaction used at
the cathode of this cell can have?
O yes, there is a minimum.
E = Ov
1.692
1.498
If so, check the "yes" box and calculate
the minimum. Round your answer to 2
decimal places. If there is no lower
limit, check the "no" box.
Ba2+ (aq) + 2e- - Ba (s)
-2.912
O no minimum
Br2 (1) + 2e - 2Br (aq)
1.066
Ca2+ (aq) + 2e-- Ca (s)
-2.868
Cl2 (g) + 2e - 2CI (aq)
Co2+ (aq) + 2e-- Co (s)
Co3+ (aq) + e - Co2+ (aq)
Cr2+ (aq) + 2e → Cr (s)
Cr3+ (aq) + 3e + Cr (s)
1.35827
Is there a maximum standard reduction
potential that the half-reaction used at
the cathode of this cell can have?
O yes, there is a maximum.
= Ov
E
-0.28
red
1.92
If so, check the "yes" box and calculate
the maximum. Round your answer to 2
decimal places. If there is no upper
limit, check the "no" box.
-0.913
O no maximum
-0.744
Cr3+ (aq) + e - Cr2+ (aq)
Cro42- (aq) + 4H20 (1) + 3e - Cr(OH)3 (s) + 50H (aq)
-0.407
-0.13
Cu2+ (aq) + 2e - Cu (s)
0.3419
By using the information in the ALEKS
Data tab, write a balanced equation
describing a half reaction that could be
used at the cathode of this cell.
Cu2+ (aq) + e- - Cut (aq)
0.153
Cu+ (aq) + e - Cu (s)
0.521
Note: write the half reaction as it would
actually occur at the cathode.
F2 (9) + 2e - 2F (aq)
2.866
Fe2+ (aq) + 2e Fe (s)
Fe+ (ag) + e - Fe2+ (aq)
Fe3+ (aq) + 3e- Fe (s)
-0.447
0.771
-0.037
Explanation
Check
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