A binary system of species 1 and 2 consists of vapor and liquid phases in equilibrium at temperature T. The overall mole fraction of species 1 in the system is z1=0.60 at temperature T. In y1 = 0.85x3 In y2 = 0.85x? Psat = 42.3 kPa Pşat = 79.7 kP Assuming the validity of the modified Raoult's Law, (a) Determine the range of pressure that this system can exist as two phases at given T and Z1. (b) For liquid mole fraction x1 = 0.47, find the pressure P and the molar fraction V of the system that is vapor. (c) Show whether or not the system exhibits an azeotrope. If an azeotrope is formed, find the azeotropic composition and pressure.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
icon
Related questions
Question
A binary system of species 1 and 2 consists of vapor and liquid phases in equilibrium at
temperature T. The overall mole fraction of species 1 in the system is z1=0.60 at temperature
T.
In y1 = 0.85x3
In y2 = 0.85x?
Pfat = 42.3 kPa
Psat = 79.7 kP
Assuming the validity of the modified Raoult's Law,
(a) Determine the range of pressure that this system can exist as two phases at given T and
Z1.
(b) For liquid mole fraction x1 = 0.47, find the pressure P and the molar fraction V of the system
that is vapor.
(c) Show whether or not the system exhibits an azeotrope. If an azeotrope is formed, find the
azeotropic composition and pressure.
Transcribed Image Text:A binary system of species 1 and 2 consists of vapor and liquid phases in equilibrium at temperature T. The overall mole fraction of species 1 in the system is z1=0.60 at temperature T. In y1 = 0.85x3 In y2 = 0.85x? Pfat = 42.3 kPa Psat = 79.7 kP Assuming the validity of the modified Raoult's Law, (a) Determine the range of pressure that this system can exist as two phases at given T and Z1. (b) For liquid mole fraction x1 = 0.47, find the pressure P and the molar fraction V of the system that is vapor. (c) Show whether or not the system exhibits an azeotrope. If an azeotrope is formed, find the azeotropic composition and pressure.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 5 steps with 12 images

Blurred answer
Similar questions
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The