Answered: 8 Calculate the partial pressure of…

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter5: Gases

Section: Chapter Questions

Problem 5.101PAE

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5-114 Carbon dioxide gas, saturated with water vapor, can be produced by the addition of aqueous acid to calcium carbonate based on the following balanced net ionic equation: (a) How many moles of wet CO (g), collected at 60.°C and 774 torr total pressure, are produced by the complete reaction of 10.0 g of CaCO3 with excess acid? (b) What volume does this wet CO2 occupy? (c) What volume would the CO2 occupy at 774 torr if a desiccant (a chemical drying agent) were added to remove the water? The vapor pressure of water at 60.°C is 149.4 mm Hg.
A mixture at 33 °C contains H2at 325 torr. N;at 475 tore and O2at 650. torr. What is the total pressure of the gases in the system? Which gas contains the greatest number of moles?
93 The complete combustion of octane can be used as a model for the burning of gasoline: 2C8H18+25O216CO2+18H2O Assuming that this equation provides a reasonable model of the actual combustion process, what volume of air at 1.0 atm and 25°C must be taken into an engine to burn 1 gallon of gasoline? (The partial pressure of oxygen in air is 0.21 atm and the density of liquid octane is 0.70 g/mL.)
5-107 If 60.0 g of NH3 occupies 35.1 L under a pressure of 77.2 in. Hg, what is the temperature of the gas, in °C?
5-118 Isooctane, which has a chemical formula C8H18 is the component of gasoline from which the term octane rating derives. (a) Write the balanced chemical equation for the combustion of isooctane. (b) The density of isooctane is 0.792 g/mL. How many kg of C02 are produced each year by the annual U.S. gasoline consumption of L? (c) What is the volume in liters of this CO2 at STP? (d) The chemical formula for isooctane can be represented by (CH3)3CCH2CH(CH3)2. Draw a Lewis structure of isooctane. (e) Another molecule with the same molecular formula is octane, which can be represented by: When comparing isooctane and octane, one structure is observed to have a boiling point of 99°C, while another is known to have a boiling point Of 125°C. Which substance, isooctane or octane, is expected to have the higher boiling point? (f) Determine whether isooctane or octane is expected to have the greater vapor pressure.
A 1.000-g sample of an unknown gas at 0C gives the following data: P(atm) V (L) 0.2500 3.1908 0.5000 1.5928 0.7500 1.0601 1.0000 0.7930 Use these data to calculate the value of the molar mass at each of the given pressures from the ideal gas law (we will call this the apparent molar mass at this pressure). Plot the apparent molar masses against pressure and extrapolate to find the molar mass at zero pressure. Because the ideal gas law is most accurate at low pressures, this extrapolation will give an accurate value for the molar mass. What is the accurate molar mass?
A 275-mL sample of CO gas is collected over water at 31C and 755 mmHg. If the temperature of the gas collection apparatus rises to 39C, what is the new volume of the sample? Assume that the barometric pressure does not change.
61 As one step in its purification, nickel metal reacts with carbon monoxide to form a compound called nickel tetracarbonyl, Ni(CO)4, which is a gas at temperature above about 316 K. A 2.000-L flask is filled with CO gas to a pressure of 748 torr at 350.0 K, and then 5.00 g of Ni is added. If the reaction describe occurs and goes to completion at constant temperature, what will the final pressure in the falsk be?
A chemist weighed out 5.14 g of a mixture containing unknown amounts of BaO(s) and CaO(s) and placed the sample in a 1.50-L flask containing CO2(g) at 30.0C and 750. torr. After the reaction to form BaCO3(s) and CaCO3(s) was completed, the pressure of CO2(g) remaining was 230. torr. Calculate the mass percentages of CaO(s) and BaO(s) in the mixture.
Pressures of gases in mixtures are referred to as partial pressures and are additive. 1.00 L of He gas at 0.75 atm is mixed with 2.00 L of Ne gas at 1.5 atm at a temperature of 25.0 C to make a total volume of 3.00 L of a mixture. Assuming no temperature change and that He and Ne can be approximated as ideal gases, what are a the total resulting pressure, b the partial pressures of each component, and c the mole fractions of each gas in the mix?
A typical barometric pressure in Kansas City is 740 torr. What is this pressure in atmospheres, in millimeters of mercury, and in kilopascals?
47 HCl(g) reacts with ammonia gas, NH3(g), to form solid ammonium chloride. If a sample of ammonia occupying 250 mL at 21 C and a pressure of 140 torr is allowed to react with excess HCl, what mass of NH4Cl will form?

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8 Calculate the partial pressure of propane (CHs) in a mixture that contains equal masses of propane and butane (CH,o) at 50°C and 764 Torr.