7) a) Assign R and S configuration to the chirality centers of molecules 28 and 29.IIICH3H.H3CCH32829IVb) Draw the structure of the major product 30, resulting from the following reaction.if you measured the optical rotation of product 30, would it be positive, negative or zero. Brieflyjustify your answer.NaOHCH3rate = k [28][NaOH]H3C2830[a]D= 45 °optical rotation of product 30c) Draw the structure of the major chiral product 31, resulting from the following reaction.H,SO4Y....CH3OH"CH329rate = k [29][CH3OH]31d) Draw the structure of the major chiral product 32, resulting from the following reaction.1) CH3MgBrrate = k [29][CH3MgBr]2) Н,О3229

From the rate equation, it is clear that all three reactions are SN^2 in nature. Hence, in all cases…

7) a) Assign R and S configuration to the chirality centers of molecules 28 and 29. II II CH3 H3C H 28 "CH3 29 IV ) Draw the structure of the major product 30, resulting from the following reaction. you measured the optical rotation of product 30, would it be positive, negative or zero. Briefly ustify your answer. NaOH CH3 rate = k [28][NaOH] H3C H 28 [a]D= 45 ° 30 optical rotation of product 30 c) Draw the structure of the major chiral product 31, resulting from the following reaction. H,SO4 CH3 CH3OH 29 rate = k [29][CH3OH] 31 d) Draw the structure of the major chiral product 32, resulting from the following reaction. 1) CHзMgBr rate = k [29][CH3M9B1] 2) H2O 29 32

7) a) Assign R and S configuration to the chirality centers of molecules 28 and 29. II II CH3 H3C H 28 "CH3 29 IV ) Draw the structure of the major product 30, resulting from the following reaction. you measured the optical rotation of product 30, would it be positive, negative or zero. Briefly ustify your answer. NaOH CH3 rate = k [28][NaOH] H3C H 28 [a]D= 45 ° 30 optical rotation of product 30 c) Draw the structure of the major chiral product 31, resulting from the following reaction. H,SO4 CH3 CH3OH 29 rate = k [29][CH3OH] 31 d) Draw the structure of the major chiral product 32, resulting from the following reaction. 1) CHзMgBr rate = k [29][CH3M9B1] 2) H2O 29 32

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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