7-15. A cyanide solution with a volume of 12.73 mL was treated with 25.00 mL of Ni²+ solution (containing excess Ni?+) to convert the cyanide into tetracyanonickelate(II): 4CN + Ni²+ → Ni(CN); The excess Ni²+ was then titrated with 10.15 mL of 0.013 07 M ethylenediaminetetraacetic acid (EDTA): Ni?+ + EDTA'- → Ni(EDTA)² Ni(CN); does not react with EDTA. If 39.35 mL of EDTA were required to react with 30.10mL of the original Ni²+ solution, calculate the molarity of CN in the 12.73-mL cyanide sample.

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7-15. A cyanide solution with a volume of 12.73 mL was treated with 25.00 mL of Ni2+
solution (containing excess Ni?+) to convert the cyanide into tetracyanonickelate(II):
4CN
+ Ni²+ → Ni(CN);
The excess Ni²+ was then titrated with 10.15 mL of 0.013 07 M
ethylenediaminetetraacetic acid (EDTA):
Ni?+ + EDTA'- → Ni(EDTA)²-
Ni(CN); does not react with EDTA. If 39.35 mL of EDTA were required to react with
30.10 nL of the original Ni²+ solution, calculate the molarity of CN in the 12.73-mL
cyanide sample.
Transcribed Image Text:7-15. A cyanide solution with a volume of 12.73 mL was treated with 25.00 mL of Ni2+ solution (containing excess Ni?+) to convert the cyanide into tetracyanonickelate(II): 4CN + Ni²+ → Ni(CN); The excess Ni²+ was then titrated with 10.15 mL of 0.013 07 M ethylenediaminetetraacetic acid (EDTA): Ni?+ + EDTA'- → Ni(EDTA)²- Ni(CN); does not react with EDTA. If 39.35 mL of EDTA were required to react with 30.10 nL of the original Ni²+ solution, calculate the molarity of CN in the 12.73-mL cyanide sample.
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