6.58 The common lead-acid car battery produces a large burst of current, even at low temperatures, and is rechargeable. The reac- tion that occurs while recharging a "dead" battery is 2PBSO,(s) + 2H,0(1) (a) Use AH values from Appendix B to calculate AHn (b) Use the following equations to check your answer to part (a): (1) Pb(s) + Pb02(s) + 2SO3(g) Pb(s) + PbO,(s) + 2H,SO,(1) 2PBSO,(s) > = -768 kJ -132 kJ AH rxn (2) SO;(g) + H,O(1) H,SO,(1) ΔΗ. FXn

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6.58 The common lead-acid car battery produces a large burst of
current, even at low temperatures, and is rechargeable. The reac-
tion that occurs while recharging a "dead" battery is
Pb(s) + PbO,(s) + 2H,SO (1)
2PBSO,(s) + 2H,0(1)
(a) Use AH values from Appendix B to calculate AHn
(b) Use the following equations to check your answer to part (a):
rxn'
2PBSO,(s)
AH an
(1) Pb(s) + Pb02(s) + 2SO3(g)
= -768 kJ
rxn
(2) SO;(g) + H,O(I)
H,SO,(1)
ΔΗ?
-132kJ
FXn
Transcribed Image Text:6.58 The common lead-acid car battery produces a large burst of current, even at low temperatures, and is rechargeable. The reac- tion that occurs while recharging a "dead" battery is Pb(s) + PbO,(s) + 2H,SO (1) 2PBSO,(s) + 2H,0(1) (a) Use AH values from Appendix B to calculate AHn (b) Use the following equations to check your answer to part (a): rxn' 2PBSO,(s) AH an (1) Pb(s) + Pb02(s) + 2SO3(g) = -768 kJ rxn (2) SO;(g) + H,O(I) H,SO,(1) ΔΗ? -132kJ FXn
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