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- Account for the following:(i) The C – Cl bond length in chlorobenzene is shorter than that in CH3 – Cl.(ii) Chloroform is stored in closed dark brown bottles.Estimate the heat released when ethene(CH2=CH2) reacts with HBr to giveCH3CH2Br. Bond enthalpies areC-H : 412 kJ/mol; C-C : 348 kJ/mol;C=C : 612 kJ/mol; C-Br : 276 kJ/mol;Br-Br : 193 kJ/mol; H-Br : 366 kJ/mol. Choose the correct answer:1. 1036 kJ/mol2. 58 kJ/mol3. 424 kJ/mol4. 200 kJ/mol5. 470 kJ/molDraw the structural formula of (3E,5Z)-5-ethyl-3,5-nonadiene. An alternative name for this compound is (3E,5Z)-5-ethylnona-3,5-diene, which follows the rules outlined in the 1993 IUPAC recommendations.
- Please draw the corresponding structure of the following compounds. CH3CH₂OH + PCC → 1. (a) 2. Br (a) [the answer from #1] + OH + H₂CRO4 → 3. Mg →Use a sheet of paper and draw structures for all the isolated, conjugated, and cumulated dienes of molecular formula C5Hg.8. Give a structural formula of the product from the following reaction: - CH, (1) "OH CH,BI (i)
- 4. Outline the following synthesis (a). Butane to 2-butanol (b). 1,2-dibromopropane from 2-propanol (c). 1-butanol to 2-butanol (d). Propane to Propene[5] Write the structure of the product of the reaction of (S)-3-bromo-3-methylhexane with ethanol (CH,CH,OH).(1) Predict the outcome of the addition of HBr to (a) trans-2-pentene, (b) 2-methyl-2-butene, and (c) 4-methylcyclohexene. How many isomers can be formed in each case? (2) Addition of HBr to 3,3-dimethyl-1-butene gives a mixture of two isomeric alkyl bromide products. Draw structures for the two products, and give a mechanistic explanation for their formation.