5. Optically pure 2-octyl sulfonate was treated with varying mixtures of water and dioxane, and the optical purity of the resulting product (2-octanol) was found to vary with the ratio of water to dioxane, as shown in the following table (J. Am. Chem. Soc. 1965, 87, 287-291). Given that dioxane possesses fairly nucleophilic oxygen atoms, provide a complete mechanism that explains the variation in in the product's optical purity due to changes in solvent composition. Hint, the solvent is doing more here than just dissolving. it is partaking in the reaction. Solvent Ratio (water : dioxane). 25:75 50: 50 75: 25 100:0 Optical purity of (S)-2-octanol. 77% 88% 95% 100% H20 OH (R)-2-0ctyl sulfonate (optically pure) (S)2-Octanol (dioane)
5. Optically pure 2-octyl sulfonate was treated with varying mixtures of water and dioxane, and the optical purity of the resulting product (2-octanol) was found to vary with the ratio of water to dioxane, as shown in the following table (J. Am. Chem. Soc. 1965, 87, 287-291). Given that dioxane possesses fairly nucleophilic oxygen atoms, provide a complete mechanism that explains the variation in in the product's optical purity due to changes in solvent composition. Hint, the solvent is doing more here than just dissolving. it is partaking in the reaction. Solvent Ratio (water : dioxane). 25:75 50: 50 75: 25 100:0 Optical purity of (S)-2-octanol. 77% 88% 95% 100% H20 OH (R)-2-0ctyl sulfonate (optically pure) (S)2-Octanol (dioane)
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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