5. [30 pts] Two short questions on previous topics: A. The following two-step mechanism has been proposed for a certain aqueous reaction Step 1: ClO + ClO → ClO2+ Cl Step 2: ClO2 + CIO→ ClO3 + Cl¯ i. Write down the balanced equation for the overall (net) reaction. ii. Laboratory experiments give the following rate law for the reaction above: Rate = k[CIO¯]² If the two-step mechanism above is correct, which is the slow step? Explain your answer based on the laboratory result. B. Draw Lewis structures for the molecules below, and show the hydrogen-bonding interaction between the two molecules using a (...) symbol. ii. iii. i. CH2=O and H₂O CH3OH and CH3OH HF and HCN Hint: the atoms of HCN are connected in the order written.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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5. [30 pts] Two short questions on previous topics:
A. The following two-step mechanism has been proposed for a certain aqueous reaction
Step 1: ClO + ClO → ClO2+ Cl
Step 2: ClO2 + CIO→ ClO3 + Cl¯
i.
Write down the balanced equation for the overall (net) reaction.
ii.
Laboratory experiments give the following rate law for the reaction above:
Rate = k[CIO¯]²
If the two-step mechanism above is correct, which is the slow step? Explain your
answer based on the laboratory result.
B. Draw Lewis structures for the molecules below, and show the hydrogen-bonding
interaction between the two molecules using a (...) symbol.
ii.
iii.
i.
CH2=O and H₂O
CH3OH and CH3OH
HF and HCN
Hint: the atoms of HCN are connected in the order written.
Transcribed Image Text:5. [30 pts] Two short questions on previous topics: A. The following two-step mechanism has been proposed for a certain aqueous reaction Step 1: ClO + ClO → ClO2+ Cl Step 2: ClO2 + CIO→ ClO3 + Cl¯ i. Write down the balanced equation for the overall (net) reaction. ii. Laboratory experiments give the following rate law for the reaction above: Rate = k[CIO¯]² If the two-step mechanism above is correct, which is the slow step? Explain your answer based on the laboratory result. B. Draw Lewis structures for the molecules below, and show the hydrogen-bonding interaction between the two molecules using a (...) symbol. ii. iii. i. CH2=O and H₂O CH3OH and CH3OH HF and HCN Hint: the atoms of HCN are connected in the order written.
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