5 A 0.400-g sample of toothpaste was boiled with a 50.00 mL solution containing citrate buffer and NaCl to extract the fluoride ion. After cooling, the solution was diluted to exactly 100.00 mL. The potential of a selective ion/calomel system in a 25.00 mL aliquot of the sample was found to be -0.1823 V. Addition of 5.00 mL of a solution containing 0.00107 mg F/mL caused the potential to change to -0.2446V. Calculate the weight-percent F in the sample

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A 0.400-g sample of toothpaste was boiled with a 50.00 mL solution containing
citrate buffer and NaCl to extract the fluoride ion. After cooling, the solution was diluted
to exactly 100.00 mL. The potential of a selective ion/calomel system in a 25.00 mL
aliquot of the sample was found to be -0.1823 V. Addition of 5.00 mL of a solution
containing 0.00107 mg F/mL caused the potential to change to -0.2446V. Calculate
the weight-percent F in the sample
Transcribed Image Text:5 A 0.400-g sample of toothpaste was boiled with a 50.00 mL solution containing citrate buffer and NaCl to extract the fluoride ion. After cooling, the solution was diluted to exactly 100.00 mL. The potential of a selective ion/calomel system in a 25.00 mL aliquot of the sample was found to be -0.1823 V. Addition of 5.00 mL of a solution containing 0.00107 mg F/mL caused the potential to change to -0.2446V. Calculate the weight-percent F in the sample
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