2) A cyanide ion selective electrode obeys the equation : E (volts) = constant - 0.05916 log [CN] The measured potential was - 0.224 V when immersed in 0.00100 M NaCN. a) What is the value of the numerical constant from the calibration equation?
2) A cyanide ion selective electrode obeys the equation : E (volts) = constant - 0.05916 log [CN] The measured potential was - 0.224 V when immersed in 0.00100 M NaCN. a) What is the value of the numerical constant from the calibration equation?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Problem Statement: Cyanide Ion Selective Electrode**
A cyanide ion selective electrode obeys the equation:
\[ E (\text{volts}) = \text{constant} - 0.05916 \log [\text{CN}^-] \]
The measured potential was \(-0.224 \, \text{V}\) when immersed in \(0.00100 \, \text{M} \, \text{NaCN}\).
**Question:**
a) What is the value of the numerical constant from the calibration equation?
**Explanation:**
This problem involves using the Nernst equation for a cyanide ion-selective electrode to determine the calibration constant. The equation relates the electrode potential \(E\) to the concentration of cyanide ions \([\text{CN}^-]\). The given potential allows us to solve for the unknown constant when the concentration of cyanide ions is specified.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fbaa64798-ff50-47d6-b342-20b56281101d%2Fd2e3f8d4-1d75-40de-8cc0-5555fb0561fd%2Fc7qxnwt_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Problem Statement: Cyanide Ion Selective Electrode**
A cyanide ion selective electrode obeys the equation:
\[ E (\text{volts}) = \text{constant} - 0.05916 \log [\text{CN}^-] \]
The measured potential was \(-0.224 \, \text{V}\) when immersed in \(0.00100 \, \text{M} \, \text{NaCN}\).
**Question:**
a) What is the value of the numerical constant from the calibration equation?
**Explanation:**
This problem involves using the Nernst equation for a cyanide ion-selective electrode to determine the calibration constant. The equation relates the electrode potential \(E\) to the concentration of cyanide ions \([\text{CN}^-]\). The given potential allows us to solve for the unknown constant when the concentration of cyanide ions is specified.
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