2) A cyanide ion selective electrode obeys the equation : E (volts) = constant - 0.05916 log [CN] The measured potential was - 0.224 V when immersed in 0.00100 M NaCN. a) What is the value of the numerical constant from the calibration equation?

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**Problem Statement: Cyanide Ion Selective Electrode**

A cyanide ion selective electrode obeys the equation:

\[ E (\text{volts}) = \text{constant} - 0.05916 \log [\text{CN}^-] \]

The measured potential was \(-0.224 \, \text{V}\) when immersed in \(0.00100 \, \text{M} \, \text{NaCN}\).

**Question:**

a) What is the value of the numerical constant from the calibration equation?

**Explanation:**

This problem involves using the Nernst equation for a cyanide ion-selective electrode to determine the calibration constant. The equation relates the electrode potential \(E\) to the concentration of cyanide ions \([\text{CN}^-]\). The given potential allows us to solve for the unknown constant when the concentration of cyanide ions is specified.
Transcribed Image Text:**Problem Statement: Cyanide Ion Selective Electrode** A cyanide ion selective electrode obeys the equation: \[ E (\text{volts}) = \text{constant} - 0.05916 \log [\text{CN}^-] \] The measured potential was \(-0.224 \, \text{V}\) when immersed in \(0.00100 \, \text{M} \, \text{NaCN}\). **Question:** a) What is the value of the numerical constant from the calibration equation? **Explanation:** This problem involves using the Nernst equation for a cyanide ion-selective electrode to determine the calibration constant. The equation relates the electrode potential \(E\) to the concentration of cyanide ions \([\text{CN}^-]\). The given potential allows us to solve for the unknown constant when the concentration of cyanide ions is specified.
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