2. Use the trendline equation from the calibration plot (that you wrote down in Table 2) to calculate the concentration of the unknown solution. Hint: the trendline equation is in the format of y = mx + b, where y is the absorbance (from Table 2) and x is the unknown concentration (that you will solve for). Try to show your work by typing into the group discussion, or you have the option to hand-write and submit a picture of your hand- written work.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Table 1**: Absorbance data recorded for five 0.200 M Fe(NO₃)₃ solutions at 20.0 °C

| Beaker | 0.0020 M Fe(NO₃)₃ (mL) | 0.0020 SCN⁻ (mL) | [FeSCN²⁺] (M) | Abs. |
|--------|------------------------|------------------|---------------|------|
| 1      | 5.0                    | 0.00             | 0.00 M        | -0.001 |
| 2      | 5.0                    | 2.00             | 8.0 x 10⁻⁵ M   | 0.278 |
| 3      | 5.0                    | 3.00             | 1.2 x 10⁻⁴ M   | 0.415 |
| 4      | 5.0                    | 4.00             | 1.6 x 10⁻⁴ M   | 0.555 |
| 5      | 5.0                    | 5.00             | 2.0 x 10⁻⁴ M   | 0.671 |

**Part I**: y = 3386x + 0.0043
R² = 0.9991

---

**Part II – Determining Concentration of an Unknown**

**Table 2**: Best-fit line and Absorbance data of unknown solution

| Best-fit line equation from Part I                        |
|-----------------------------------------------------------|
|                                                           |
| Absorbance reading of unknown                             |
| 0.338                                                     |

---

**Part III – Determining the Equilibrium Constant**

| Test tube | 0.0020 M Fe(NO₃)₃ (mL) | 0.0020 SCN⁻ (mL) | H₂O (mL) | Abs. | Net Abs |
|-----------|------------------------|------------------|----------|------|---------|
| 1         | 3.00                   | 0.00             | 7.00     | 0.000| ------- |
| 2         | 3.00                   | 2.00             | 5.00     | 0.119| 0.
Transcribed Image Text:**Table 1**: Absorbance data recorded for five 0.200 M Fe(NO₃)₃ solutions at 20.0 °C | Beaker | 0.0020 M Fe(NO₃)₃ (mL) | 0.0020 SCN⁻ (mL) | [FeSCN²⁺] (M) | Abs. | |--------|------------------------|------------------|---------------|------| | 1 | 5.0 | 0.00 | 0.00 M | -0.001 | | 2 | 5.0 | 2.00 | 8.0 x 10⁻⁵ M | 0.278 | | 3 | 5.0 | 3.00 | 1.2 x 10⁻⁴ M | 0.415 | | 4 | 5.0 | 4.00 | 1.6 x 10⁻⁴ M | 0.555 | | 5 | 5.0 | 5.00 | 2.0 x 10⁻⁴ M | 0.671 | **Part I**: y = 3386x + 0.0043 R² = 0.9991 --- **Part II – Determining Concentration of an Unknown** **Table 2**: Best-fit line and Absorbance data of unknown solution | Best-fit line equation from Part I | |-----------------------------------------------------------| | | | Absorbance reading of unknown | | 0.338 | --- **Part III – Determining the Equilibrium Constant** | Test tube | 0.0020 M Fe(NO₃)₃ (mL) | 0.0020 SCN⁻ (mL) | H₂O (mL) | Abs. | Net Abs | |-----------|------------------------|------------------|----------|------|---------| | 1 | 3.00 | 0.00 | 7.00 | 0.000| ------- | | 2 | 3.00 | 2.00 | 5.00 | 0.119| 0.
## Post-Lab Questions:

### Part I – Creating a Calibration Line

1. **Compare the color of the solutions in each of the five test tubes in Part I.** Recall from the introduction that the product FeSCN^2+ has a deep red color. In 1-2 sentences, explain what you think the color changes indicate for the equilibrium of these reaction solutions.

### Part II – Determining the Concentration of an Unknown

2. **Use the trendline equation from the calibration plot (that you wrote down in Table 2) to calculate the concentration of the unknown solution.** 
   *Hint: the trendline equation is in the format of y = mx + b, where y is the absorbance (from Table 2) and x is the unknown concentration (that you will solve for).* 
   * Try to show your work by typing into the group discussion, or you have the option to hand-write and submit a picture of your handwritten work.

### Part III – Determining the Equilibrium Constant

3. **Refer to the absorbance data you wrote down in Table 3. Use the same trendline equation from the calibration plot (from Part II, Table 2) to calculate the concentration of the solution from test tube #2.**
   *Hint: follow the same procedure as question 2, but use the net absorbance of test tube #2 to plug in for y.*
   * Show your work (either typed or hand-written).

4. **Calculate the initial concentration of Fe^3+ in test tube #2.** 
   *Hint: use M₁V₁ = M₂V₂, where V₂ is a total of 10.0 mL.* 
   * Show your work.

5. **Calculate the initial concentration of SCN^- in test tube #2, where again V₂ is 10.0 mL.** 
   * Show your work.

6. **Write and fill out the following ICE table, using concentrations for test tube #2.** 
   *Hint: the initial concentrations of Fe^3+ and SCN^- were calculated in questions 4 and 5, and the equilibrium concentration of FeSCN^2+ was calculated in question 3.*

|        | [Fe^3+]        | +    | [SCN^-]       |         ⥫     | [FeSCN^2+]     |
|
Transcribed Image Text:## Post-Lab Questions: ### Part I – Creating a Calibration Line 1. **Compare the color of the solutions in each of the five test tubes in Part I.** Recall from the introduction that the product FeSCN^2+ has a deep red color. In 1-2 sentences, explain what you think the color changes indicate for the equilibrium of these reaction solutions. ### Part II – Determining the Concentration of an Unknown 2. **Use the trendline equation from the calibration plot (that you wrote down in Table 2) to calculate the concentration of the unknown solution.** *Hint: the trendline equation is in the format of y = mx + b, where y is the absorbance (from Table 2) and x is the unknown concentration (that you will solve for).* * Try to show your work by typing into the group discussion, or you have the option to hand-write and submit a picture of your handwritten work. ### Part III – Determining the Equilibrium Constant 3. **Refer to the absorbance data you wrote down in Table 3. Use the same trendline equation from the calibration plot (from Part II, Table 2) to calculate the concentration of the solution from test tube #2.** *Hint: follow the same procedure as question 2, but use the net absorbance of test tube #2 to plug in for y.* * Show your work (either typed or hand-written). 4. **Calculate the initial concentration of Fe^3+ in test tube #2.** *Hint: use M₁V₁ = M₂V₂, where V₂ is a total of 10.0 mL.* * Show your work. 5. **Calculate the initial concentration of SCN^- in test tube #2, where again V₂ is 10.0 mL.** * Show your work. 6. **Write and fill out the following ICE table, using concentrations for test tube #2.** *Hint: the initial concentrations of Fe^3+ and SCN^- were calculated in questions 4 and 5, and the equilibrium concentration of FeSCN^2+ was calculated in question 3.* | | [Fe^3+] | + | [SCN^-] | ⥫ | [FeSCN^2+] | |
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