2. Oxalic acid (a diprotic acid HOOCCOOH; pKal 1.25 and pKa2 = 4.28 at 25°C) is added to pure water at a concentration of 10-2 M. Determine the final pH to the nearest 0.001 pH unit at equilibrium and the concentration of all species using: an exact solution. Assume 25°C and ionic strength effects are negligible. (5 marks) b. an algebraic approximation. Check your assumptions and compare the solution in part (a) (5 marks) a. =
2. Oxalic acid (a diprotic acid HOOCCOOH; pKal 1.25 and pKa2 = 4.28 at 25°C) is added to pure water at a concentration of 10-2 M. Determine the final pH to the nearest 0.001 pH unit at equilibrium and the concentration of all species using: an exact solution. Assume 25°C and ionic strength effects are negligible. (5 marks) b. an algebraic approximation. Check your assumptions and compare the solution in part (a) (5 marks) a. =
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:2.
Oxalic acid (a diprotic acid HOOCCOOH; pKal
1.25 and pKa2 = 4.28 at 25°C) is added to pure water
at a concentration of 10-2 M. Determine the final pH to the nearest 0.001 pH unit at equilibrium and
the concentration of all species using:
an exact solution. Assume 25°C and ionic strength effects are negligible. (5 marks)
b.
an algebraic approximation. Check your assumptions and compare the solution in part (a)
(5 marks)
a.
=
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