2. Br₂ a Proton transfer b= Lewis acid/base c = Radical chain substitution 1. 2. CH₂OH conc. HBr OCH₂ Br OH d = Radical chain addition e = Electrophilic addition f=E1 Elimination HBr Br Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. = E2 Elimination h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution
2. Br₂ a Proton transfer b= Lewis acid/base c = Radical chain substitution 1. 2. CH₂OH conc. HBr OCH₂ Br OH d = Radical chain addition e = Electrophilic addition f=E1 Elimination HBr Br Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. = E2 Elimination h = SN1 Nucleophilic substitution i = SN2 Nucleophilic substitution
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Reaction Mechanisms Identification
This exercise involves analyzing two chemical reactions and identifying their mechanisms from the options provided. Below are the reaction equations and the list of possible mechanisms.
#### Reaction 1:
\[ \text{Isobutane (CH}_3)_2\text{CH}_2 + \text{Br}_2 \rightarrow \text{(CH}_3)_2\text{CBrOCH}_3 + \text{HBr} \]
This reaction involves the conversion of isobutane with bromine to form a bromomethane compound and hydrobromic acid.
#### Reaction 2:
\[ \text{2-Methylbut-2-ene} + \text{conc. HBr} \rightarrow \text{2-Methylbutan-2-ol} + \text{t-Butyl bromide} \]
This reaction involves treating 2-methylbut-2-ene with concentrated hydrobromic acid to form 2-methylbutan-2-ol and t-butyl bromide.
### Possible Mechanisms:
- **a** = Proton transfer
- **b** = Lewis acid/base
- **c** = Radical chain substitution
- **d** = Radical chain addition
- **e** = Electrophilic addition
- **f** = E1 Elimination
- **g** = E2 Elimination
- **h** = S<sub>N</sub>1 Nucleophilic substitution
- **i** = S<sub>N</sub>2 Nucleophilic substitution
### Instructions
Identify the mechanism by which each of the reactions above proceeds. Use the letters (a - i) for your answers.
**1.** [ ]
**2.** [ ]
### Explanation
- **Reaction 1** likely proceeds through a radical substitution mechanism (option c), as it involves halogenation of an alkane with bromine, typical for radical chain reactions.
- **Reaction 2** could proceed through an electrophilic addition mechanism (option e), as it involves addition of HBr to an alkene.
Please write your answers in the boxes provided.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F4f7442e5-ed1a-4154-ba5d-4813abad6cff%2Fde69bfdd-b420-4577-ac96-83e13f9d0b05%2Fxlony1f_processed.png&w=3840&q=75)
Transcribed Image Text:### Reaction Mechanisms Identification
This exercise involves analyzing two chemical reactions and identifying their mechanisms from the options provided. Below are the reaction equations and the list of possible mechanisms.
#### Reaction 1:
\[ \text{Isobutane (CH}_3)_2\text{CH}_2 + \text{Br}_2 \rightarrow \text{(CH}_3)_2\text{CBrOCH}_3 + \text{HBr} \]
This reaction involves the conversion of isobutane with bromine to form a bromomethane compound and hydrobromic acid.
#### Reaction 2:
\[ \text{2-Methylbut-2-ene} + \text{conc. HBr} \rightarrow \text{2-Methylbutan-2-ol} + \text{t-Butyl bromide} \]
This reaction involves treating 2-methylbut-2-ene with concentrated hydrobromic acid to form 2-methylbutan-2-ol and t-butyl bromide.
### Possible Mechanisms:
- **a** = Proton transfer
- **b** = Lewis acid/base
- **c** = Radical chain substitution
- **d** = Radical chain addition
- **e** = Electrophilic addition
- **f** = E1 Elimination
- **g** = E2 Elimination
- **h** = S<sub>N</sub>1 Nucleophilic substitution
- **i** = S<sub>N</sub>2 Nucleophilic substitution
### Instructions
Identify the mechanism by which each of the reactions above proceeds. Use the letters (a - i) for your answers.
**1.** [ ]
**2.** [ ]
### Explanation
- **Reaction 1** likely proceeds through a radical substitution mechanism (option c), as it involves halogenation of an alkane with bromine, typical for radical chain reactions.
- **Reaction 2** could proceed through an electrophilic addition mechanism (option e), as it involves addition of HBr to an alkene.
Please write your answers in the boxes provided.
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