H,SO4 1. H20 n-Bu 2. Na NH2 CN 2 Br NaBr NH3 toluene, reflux n-Bu a = Proton transfer d = Radical chain addition g= E2 Elimination b = Lewis acid/base e = Electrophilic addition h = Syl Nucleophilic substitution c = Radical chain substitution f=El Elimination i= SN2 Nucleophilic substitution Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. 1.
H,SO4 1. H20 n-Bu 2. Na NH2 CN 2 Br NaBr NH3 toluene, reflux n-Bu a = Proton transfer d = Radical chain addition g= E2 Elimination b = Lewis acid/base e = Electrophilic addition h = Syl Nucleophilic substitution c = Radical chain substitution f=El Elimination i= SN2 Nucleophilic substitution Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers. 1.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Reaction Mechanisms Identification**
---
**1. Reaction Details:**
- **Reactants:**
- Starting compound with a hydroxyl group (OH) attached to a cyclohexane ring.
- Reagent: H₂SO₄ (sulfuric acid).
- **Products:**
- A compound with a double bond between two cyclohexane rings.
- Water (H₂O).
**2. Reaction Details:**
- **Reactants:**
- A compound with a cyano group (CN) attached to a butyl chain.
- 2 equivalents of an alkyl bromide.
- **Reagents:**
- Sodium amide (NaNH₂).
- Solvent: Toluene, heated under reflux conditions.
- **Products:**
- A cyano compound with an elongated butyl chain (n-Bu).
- Sodium bromide (NaBr).
- Ammonia (NH₃).
**Mechanism Options:**
- **a:** Proton transfer
- **b:** Lewis acid/base
- **c:** Radical chain substitution
- **d:** Radical chain addition
- **e:** Electrophilic addition
- **f:** E1 Elimination
- **g:** E2 Elimination
- **h:** Sₙ1 Nucleophilic substitution
- **i:** Sₙ2 Nucleophilic substitution
**Instruction:**
Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers.
1. [ ]
2. [ ]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb1a68961-4ff0-4515-a729-3be4df9f661e%2Ff9400f31-fb2d-4465-a633-77bbca2bbbd0%2Fo3trxuy_processed.png&w=3840&q=75)
Transcribed Image Text:**Reaction Mechanisms Identification**
---
**1. Reaction Details:**
- **Reactants:**
- Starting compound with a hydroxyl group (OH) attached to a cyclohexane ring.
- Reagent: H₂SO₄ (sulfuric acid).
- **Products:**
- A compound with a double bond between two cyclohexane rings.
- Water (H₂O).
**2. Reaction Details:**
- **Reactants:**
- A compound with a cyano group (CN) attached to a butyl chain.
- 2 equivalents of an alkyl bromide.
- **Reagents:**
- Sodium amide (NaNH₂).
- Solvent: Toluene, heated under reflux conditions.
- **Products:**
- A cyano compound with an elongated butyl chain (n-Bu).
- Sodium bromide (NaBr).
- Ammonia (NH₃).
**Mechanism Options:**
- **a:** Proton transfer
- **b:** Lewis acid/base
- **c:** Radical chain substitution
- **d:** Radical chain addition
- **e:** Electrophilic addition
- **f:** E1 Elimination
- **g:** E2 Elimination
- **h:** Sₙ1 Nucleophilic substitution
- **i:** Sₙ2 Nucleophilic substitution
**Instruction:**
Identify the mechanism by which each of the reactions above proceeds from among the mechanisms listed. Use the letters a - i for your answers.
1. [ ]
2. [ ]
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