2. a) Calculate the hard-sphere (HS) collision theory rate constant ks for the reaction NO(g) + C₁₂(g) Þ NOCl(g) + HS Cl(g) at 300 K in units of dm³ mols. The collision diameters of NO and Cl₂ are 370 and 540 pm, respectively. 16.0 g/mol, and mcı Use masses of m₁ = 14.0 g/mol, mo = 35.0 g/mol. N = b) Now include the line-of-centers (LOC) energy criterion to find koc in units of dm³ mol¹ s¹ using E₁ = 84.9 kJ mol LOC LOC c) Calculate the ratio of kчs and kLoc to the experimental rate constant at 300 K given A = 3.981 10° dm³ mol¹ s and E₁ = 84.9 kJ mol‍¹. a -1

2. a) Calculate the hard-sphere (HS) collision theory rate constant ks for the reaction NO(g) + C₁₂(g) Þ NOCl(g) + HS Cl(g) at 300 K in units of dm³ mols. The collision diameters of NO and Cl₂ are 370 and 540 pm, respectively. 16.0 g/mol, and mcı Use masses of m₁ = 14.0 g/mol, mo = 35.0 g/mol. N = b) Now include the line-of-centers (LOC) energy criterion to find koc in units of dm³ mol¹ s¹ using E₁ = 84.9 kJ mol LOC LOC c) Calculate the ratio of kчs and kLoc to the experimental rate constant at 300 K given A = 3.981 10° dm³ mol¹ s and E₁ = 84.9 kJ mol‍¹. a -1

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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