180- 29- 4800 3.0 Proton NMA 2959.18 2908.03 3080 2074 30 2.5 1H 1H pepojamempopesyonpapanpar 230 220 210 200 190 PPM Carbon 13 NMA 2500 HAVENUMBERS 2.0 2000 70 60 1710.00- 1H M 1.5 1400.30 1377.35 1500 2H 1.5H sc cor CC 201 1000 843. 1.5H 1.0 PPM 20 10 PPM 0 MF C8H160 MW 128 %C 74.9 %H 12.6 0.5
180- 29- 4800 3.0 Proton NMA 2959.18 2908.03 3080 2074 30 2.5 1H 1H pepojamempopesyonpapanpar 230 220 210 200 190 PPM Carbon 13 NMA 2500 HAVENUMBERS 2.0 2000 70 60 1710.00- 1H M 1.5 1400.30 1377.35 1500 2H 1.5H sc cor CC 201 1000 843. 1.5H 1.0 PPM 20 10 PPM 0 MF C8H160 MW 128 %C 74.9 %H 12.6 0.5
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:### Transcription of Spectroscopy Data
#### Molecular Information
- **Molecular Formula (MF):** C₈H₁₆O
- **Molecular Weight (MW):** 128
- **% Carbon (%C):** 74.9
- **% Hydrogen (%H):** 12.6
#### Infrared (IR) Spectroscopy
- The IR spectrum is plotted with % Transmittance on the y-axis and Wavenumbers on the x-axis, ranging from 4000 to 600 cm⁻¹.
- Key Absorption Peaks:
- Around 2954.08 and 2874.26 cm⁻¹: indicative of C-H stretching.
- A sharp peak at 1711.68 cm⁻¹, likely representing C=O stretching.
- Peaks at 1460.23 and 1377.20 cm⁻¹: possibly due to CH₂ and CH₃ bending vibrations.
- Other peaks include 1169.59, 1109.39, and 721.00 cm⁻¹, suggestive of various C-C and C-O stretching or bending modes.
#### Proton Nuclear Magnetic Resonance (¹H NMR)
- The ¹H NMR spectrum shows chemical shifts (ppm) on the x-axis, with peaks indicating the environment of hydrogen atoms:
- Peaks around 2.5 ppm labeled "1H 1H" likely due to protons on carbons adjacent to electronegative groups.
- A peak around 1.5 ppm labeled "2H" indicates protons in a specific chemical environment, possibly adjacent to carbonyl groups.
- Peaks labeled "1.5H" around 1.5 ppm suggest overlapping environments.
#### Carbon-13 Nuclear Magnetic Resonance (¹³C NMR)
- The ¹³C NMR shows peaks with chemical shifts in ppm:
- Peaks range between 10 to 100 ppm, common for sp³ hybridized carbon atoms.
- Specific peaks can indicate particular carbon types such as methyl, methylene, or methine groups.
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