(11-6) If the partial pressure of the carbon dioxide in the gas in contact with leachate within a landfill is one atmosphere, estimate the pH of the leachate. Assume the carbon dioxide in the landfill gas is the only factor affecting the pH of the leachate
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(11-6) If the partial pressure of the carbon dioxide in the gas in contact with leachate within a landfill is one atmosphere, estimate the pH of the leachate. Assume the carbon dioxide in the landfill gas is the only factor affecting the pH of the leachate
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- (b) Sodium hydroxide reacts with propanoic acid in the following equation: NaOH + CH3CH,COOHCH3CH2COONA + HLO A buffer solution is formed when sodium hydroxide is added to an excess of aqueous propanoic acid. (i) Calculate the number of moles of propanoic acid in 50.0 cm of 0.125 mol dm aqueous propanoic acid. (ii) Use your answers to part (b)(i) to calculate the number of moles of propanoic acid in the buffer solution when 2.00 cm' of 0.500 mol dm aqueous sodium -3 hydroxide are added to 50.0 cm' of 0.125 mol dm aqueous propanoic acid. ) Hence calculate the pH of this buffer solution at 298.15 K.11. (ii) A student was given 400 cm of aqueous ammonia solution, NH,(ag), The student was asked to determine how many moles of NH, had been dissolved to prepare the solution. The student titrated 25.0cm of NH.(ag) and found that it reacted exactiy with 32.5cm3 of 0.100 mol dm sulturic acid. The equation for this reaction is shown below. 2NH,(aq) + H,SO,(aq) → (NH)SO,(aq) Calculate the amount, in moles, of NH, in the original 400 cm3 solution. mol answer =6. (a) Aspirin is a weak acid with a pKa of 3.6 and MW 180 g/mol. The saturation solubility (S) of aspirin in water is 3.3 g /L and a saturated solution has pH equal to your answer to question 4(b) above. What is the solubility of the unionised form (So) of aspirin at this pH using units of mol/L and g/L. (b) Use the So value (just obtained) to calculate the saturation solubility (S) of aspirin in water at pH 6.6 using units of mol/L and g/L. (c) If you modified the aspirin suspension APF12 formula by replacing the purified water with pH 6.6 buffer, would the product be a suspension or solution?
- What is the equilibrium constant value for NaC2H3O2 and how do you find its Kb?7-11. Limestone consists mainly of the mineral calcite, CaCO3. The carbonate content of 0.541 3 g of powdered limestone was measured by suspending the powder in water, adding 10.00 mL of 1.396 M HCI, and heating to dissolve the solid and expel CO2: CACO3 (s) +2H* → Ca²* +CO,T +H2O Calcium carbonate FM 100.086 The excess acid required 39.96 mL of 0.100 4 M NaOH for complete titration to a phenolphthalein end point. Find the weight percent of calcite in the limestone.(1) Careless Carlie weighed her KHP sample, but forgot to bring her report sheet along, so she recorded the mass of KHP on a paper towel. During her titration, which required 18.46 mL of base, she spilled some base on her hands. She remembered to wash her hands, but forgot about the data on the towel, and used it to dry her hands. When she went to calculate the molarity of the base, Carlie discovered that she didn’t have the mass of her KHP. Her kindhearted instructor told Carlie that her base was 0.2987 M. Calculate the mass of Carlie’s KHP sample. Show calculations (2) What mass of solid NaOH would be needed to make 645 mL of Carlie’s NaOH solution? Show calculations.
- One strategy for dealing with the acidification of lakes is periodically to add powered limestone (CaCO3) to them, resulting in pH of 10.95. Calculate the Ca2+ concentration in the lake. CO2 in atmosphere 370 ppm KH,CO2 = 0.033 mol/(L∙atm) Ka1 = 10-6.3 Ka2 = 10-10.3 Ksp,CaCO3 = 4.57 x 10-9A 12.63 g sample of calcium ore was dissolved in HCl and gravimetrically analyzed, through the precipitation of calcium into CaC2O4 · H2O. The precipitate was filtered, washed, dried, and ignited at 500 oC until the weight was constant, giving a final mass of 2.35 grams pure CaCO3 (100.087 g/mol). Calculate the % Calcium (40.078 g/mol) in the sample.A chemist wishes to precipitate yttrium cations out of a 1.00 L solution. if the concentration of (in solution is 0.428 M and the K of yttrium iodate is 1.12 x 10, what mass of potassium lodate (00 must be added so that precipitation may begin? The molar mass of potassium lodate is 21A.00 g/mol. (27) (A) (B) (C) (D) 91.6g 64.0 ug (6.4 x 10* g) 411 mg 56.0 ng 137 mg (5.6 x 10* g) (E)
- Calculate the analytical concentration of a 1:1 dilution of concentrated ammonium hydroxide? Mixture of 1 part ammonia, to one part waterHBR, O2, CH3OH all have comparable molecular masses. List the dominant type of IMF for the pure substances, then rank the strength of each compound based on IMFs within the samples. (1 = strongest 2= in between 3 = weakest ) Substance IMF Relative Strength HBR O2 CH3OHa) Calculate the pH of an aqueous solution of the salt NaA, which was made to a concentration of 0.080 M NaA. The Ka of the weak acid HA is 2.0 x 10-5. Your pH should go to two places past the decimal point (i.e. 1.35). b) Aniline, C6H5NH2, has a pKb of 9.40. What is the pH of a solution which is 0.12 M in aniline and 0.38 M in anilinium ion, C6H5NH3+? Your answer should be to two places past the decimal.
