10. Acid chlorides are obtained by treating carboxylic acid with A) HCI C)SOCI, B)CI, D) NaCI

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
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Answer Q16, 17, 18

Questions 10-49
DIRECTIONS: Each of the following questions
or incomplete statements below is followed
by four suggested answers lettered A D.
Solect or choose the letters of the best answer
to the question or incomptete statement.
Que
The real
10. Acid chtorides are obtained by treating
Carboxylic acid with
A) HCI
C)SOCI,
B) CI
D) NaCI
Suitabie
yield can
ckds is slow
227
A) conc
B) dif.
C) Na
DI ca
10.
Which one of the following aubstances is
the main organic product when CICH COOH
Is refluxed with aqueous NaOH?.
A) CICH COONa
B) HOCH COOH
C) OHCH COONA
D) NAOCH COOH
Arrango the following compounds in order
of their increasing strengths as acids putting
the weakest first
1) CH CO H.
3) CH CICO H
A) 1>2> 3
C) 3>1> 2
17
2) CH,CH,CO H
B) 2 > 3>1
What
D) 2<1<3
rever
A)
B)
C)
D)
11.
Which one of the following substances
Would be oxidised to 2- methyipropanoi (CH CO C H.) from ethanol and othanoic acid, a
acid?
A) CH CH CH(OH)CH,
B) (CH) CHOH
C) (CH.),CHCH,OH
D) (CH) CHCHCH OH
12. Which one of the following carboxylic acids
is the strongest?
A) CHF CH COOH
B) CH FCH COOH
C) CH CHFCOOH
D) CH,FCHFCOOH
Questions 18 and 19
In the laboratory proparation of ethylethanate
little concentrated sulphunc acid is added to the
reaction mixture.
Th
25
in
18 What is the purpose of the concentrated
sulphuric acid
A) to polarised the alcohol
B) to inhibit the reaction
C) to cause the reaction to go faster
D) to acidify the medium
is
19. What is the general name for this type of
reaction?
A) esterification B) ethanoylation
C) acylation
13,
When phenylmethanoate is hydrolysed by
excess NaOH(aq), the products of the reaction
D) saponification
are
26
The systematic name of the compound with
structural formula
20
A) phenoxide ion and methanol
B) phenol and methanoate ion
C) benzoate ion and methanol
D) phonol and methanoic acid
HOH
%3D
14.
is
To which of the following classes of organic
compounds does
HOC H
A) ethanedioic acid
B) transbutanedioic acid
C) transbutenedioic acid
D) cis butanedioic acid
CH-0-C
belong?
A) aldehydes
C) esters
B) carboxylic acid
D) Ketones
21. Name the compound with tormula
CH CICOCI
A) 1, 2 -dichloro ethanone
B) chloroethanyl chloride
C) 1, 2- dichloro ethanal
D) dichloro ethanoyl chloride
15. An ester was reflux with aqueous sodium
hydroxide and then distilled. The distillate
gave a yellow precipitate on warming wilth
iodine in aqueous sodium hydroxide. The
residue in the flask gave a white precipitate
when dilute hydrochloric acid was added. A
possible forumula for the orginal ester is
A) CH,CO,C,H,
B) CH,CO,CH,
C) CH,CH,CHO CH,
D) CH,CO,CH,CH,
22. Arranging the following inorder of increasing
acid strength starting with the least acidic we
have:
A) CH,CH,CO,H, CH,CICO,H, CH CO.H, HCO,H
B) HCO,H, CH,CO,H, CH,CICO,H, CH,CH,CO,H
C) CH,CH,CO,H, HCO,H, CH.CO,H, CH,CiCO,H
D) CH,CH,CO,H, C,H,CO,H, HOO,H, CH,CICO,H
354
Transcribed Image Text:Questions 10-49 DIRECTIONS: Each of the following questions or incomplete statements below is followed by four suggested answers lettered A D. Solect or choose the letters of the best answer to the question or incomptete statement. Que The real 10. Acid chtorides are obtained by treating Carboxylic acid with A) HCI C)SOCI, B) CI D) NaCI Suitabie yield can ckds is slow 227 A) conc B) dif. C) Na DI ca 10. Which one of the following aubstances is the main organic product when CICH COOH Is refluxed with aqueous NaOH?. A) CICH COONa B) HOCH COOH C) OHCH COONA D) NAOCH COOH Arrango the following compounds in order of their increasing strengths as acids putting the weakest first 1) CH CO H. 3) CH CICO H A) 1>2> 3 C) 3>1> 2 17 2) CH,CH,CO H B) 2 > 3>1 What D) 2<1<3 rever A) B) C) D) 11. Which one of the following substances Would be oxidised to 2- methyipropanoi (CH CO C H.) from ethanol and othanoic acid, a acid? A) CH CH CH(OH)CH, B) (CH) CHOH C) (CH.),CHCH,OH D) (CH) CHCHCH OH 12. Which one of the following carboxylic acids is the strongest? A) CHF CH COOH B) CH FCH COOH C) CH CHFCOOH D) CH,FCHFCOOH Questions 18 and 19 In the laboratory proparation of ethylethanate little concentrated sulphunc acid is added to the reaction mixture. Th 25 in 18 What is the purpose of the concentrated sulphuric acid A) to polarised the alcohol B) to inhibit the reaction C) to cause the reaction to go faster D) to acidify the medium is 19. What is the general name for this type of reaction? A) esterification B) ethanoylation C) acylation 13, When phenylmethanoate is hydrolysed by excess NaOH(aq), the products of the reaction D) saponification are 26 The systematic name of the compound with structural formula 20 A) phenoxide ion and methanol B) phenol and methanoate ion C) benzoate ion and methanol D) phonol and methanoic acid HOH %3D 14. is To which of the following classes of organic compounds does HOC H A) ethanedioic acid B) transbutanedioic acid C) transbutenedioic acid D) cis butanedioic acid CH-0-C belong? A) aldehydes C) esters B) carboxylic acid D) Ketones 21. Name the compound with tormula CH CICOCI A) 1, 2 -dichloro ethanone B) chloroethanyl chloride C) 1, 2- dichloro ethanal D) dichloro ethanoyl chloride 15. An ester was reflux with aqueous sodium hydroxide and then distilled. The distillate gave a yellow precipitate on warming wilth iodine in aqueous sodium hydroxide. The residue in the flask gave a white precipitate when dilute hydrochloric acid was added. A possible forumula for the orginal ester is A) CH,CO,C,H, B) CH,CO,CH, C) CH,CH,CHO CH, D) CH,CO,CH,CH, 22. Arranging the following inorder of increasing acid strength starting with the least acidic we have: A) CH,CH,CO,H, CH,CICO,H, CH CO.H, HCO,H B) HCO,H, CH,CO,H, CH,CICO,H, CH,CH,CO,H C) CH,CH,CO,H, HCO,H, CH.CO,H, CH,CiCO,H D) CH,CH,CO,H, C,H,CO,H, HOO,H, CH,CICO,H 354
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