1.6 0.7 1.4 D 0.6 1.2 Soret 0.5 0.4 0.8 COOCH 0.3 0.6 phytyl bacteriochlorophyll a 0.2 0.4 Qx 0.1 0.2 700 750 800 850 900 2 (nm) 300 400 500 600 700 800 2 (nm) Figure 4.7 Absorption (left) and fluorescence (right) spectra of bacteriochlorophyll a in diethyl ether Look at this figure from Blankenship's book, Molecular Mechanisms of Photosynthesis. You can see the structure for bacteriochlorophyll a, along with its absorption spectrum. a. What is the molecular shape around the labeled carbon atom? b. What is the hybridization around that same carbon? c. Based on this structure, would you expect this molecule to absorb light in the visible spectrum? Why or why not? Absorbance Fluorescence (Arbitrary units)
1.6 0.7 1.4 D 0.6 1.2 Soret 0.5 0.4 0.8 COOCH 0.3 0.6 phytyl bacteriochlorophyll a 0.2 0.4 Qx 0.1 0.2 700 750 800 850 900 2 (nm) 300 400 500 600 700 800 2 (nm) Figure 4.7 Absorption (left) and fluorescence (right) spectra of bacteriochlorophyll a in diethyl ether Look at this figure from Blankenship's book, Molecular Mechanisms of Photosynthesis. You can see the structure for bacteriochlorophyll a, along with its absorption spectrum. a. What is the molecular shape around the labeled carbon atom? b. What is the hybridization around that same carbon? c. Based on this structure, would you expect this molecule to absorb light in the visible spectrum? Why or why not? Absorbance Fluorescence (Arbitrary units)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:PHOTOSYNTHETIC PIGMENTS
1.6
0.7
1.4
Qy
CH
0.6
1.2
Soret
0.5
1
H
0.4
0.8
0.3
COOCH
0.6
phytyl bacteriochlorophyll a
0.2
0.4
Qx
0.1
0.2
300
400
500
600
700
800
700 750 800 850 900
2 (nm)
2 (nm)
Figure 4.7 Absorption (left) and fluorescence (right) spectra of bacteriochlorophyll a in diethyl ether
5. Look at this figure from Blankenship's book, Molecular Mechanisms of Photosynthesis.
You can see the structure for bacteriochlorophyll a, along with its absorption spectrum.
a. What is the molecular shape around the labeled carbon atom?
b. What is the hybridization around that same carbon?
c. Based on this structure, would you expect this molecule to absorb light in the
visible spectrum? Why or why not?
Absorbance
Fluorescence (Arbitrary units)
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