1. The Guam bubble snail (Haminoea cymbalum) contains kumepaloxane, a chemical signal agent discharged when this mollusk is disturbed by predatory carnivorous fish. The biosynthesis of kumepaloxane is thought to occur via an enzymatic equivalent of a "Br₂/ H₂O" - halohydrin formation. ICH 3 Br₂ Precursor? (R) .... (R) (S) (S) (E) HBr Kumepaloxane Br Draw the structure of the precursor to kumepaloxane which is an alkene alcohol. Write a detailed mechanism by which the alkene alcohol in part (a) is converted to kumepaloxane when Br2 (no light and no perxoxide) is added. What is the other stereoisomer of kumepaloxane that could be formed?
1. The Guam bubble snail (Haminoea cymbalum) contains kumepaloxane, a chemical signal agent discharged when this mollusk is disturbed by predatory carnivorous fish. The biosynthesis of kumepaloxane is thought to occur via an enzymatic equivalent of a "Br₂/ H₂O" - halohydrin formation. ICH 3 Br₂ Precursor? (R) .... (R) (S) (S) (E) HBr Kumepaloxane Br Draw the structure of the precursor to kumepaloxane which is an alkene alcohol. Write a detailed mechanism by which the alkene alcohol in part (a) is converted to kumepaloxane when Br2 (no light and no perxoxide) is added. What is the other stereoisomer of kumepaloxane that could be formed?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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