1. Predict Products. Using line structures, give the major product. Rearrangements are possible. DON'T SHOW MECHANISMS HERE. Use scratch paper if needed. NR if no reaction; indicate stereochemistry as we have discussed (E=enantiomer; D = Diastereomer) HCI a hot HCI cold Br2 FeBr3 HNO3 d. H2SO4 CI NR is not this answer. AICI3

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### Predicting Products in Organic Reactions

**Instructions:**
Using line structures, give the major product for each of the following reactions. Rearrangements are possible. **Do not show mechanisms here**. Use scratch paper if needed. NR if no reaction; indicate stereochemistry as we have discussed (E = enantiomer; D = diastereomer).

#### Reactions:

**a.**
\[ \text{CH}_3-CH=CH-CH_3 \xrightarrow{\text{HCl, hot}} ? \]

**b.**
\[ \text{CH}_3-CH=CH-CH_3 \xrightarrow{\text{HCl, cold}} ? \]

**c.**
![Benzene ring] \xrightarrow{\text{Br}_2, \text{FeBr}_3} ? \]

**d.**
![T-butanol with benzene ring] \xrightarrow{\text{HNO}_3, \text{H}_2\text{SO}_4} ? \]

**e.**
![Methoxy benzene] \xrightarrow{\text{tert-butyl chloride, AlCl}_3} ? \]

Note: NR is not the answer for any of these reactions.

### Additional Explanation:

- **Reaction a and b:** Focuses on the addition of HCl to an alkene. The condition (hot and cold) can impact the product structure.
- **Reaction c:** Aromatic bromination using Br₂ and FeBr₃, a common electrophilic aromatic substitution.
- **Reaction d:** Nitration using HNO₃ and H₂SO₄, another example of electrophilic aromatic substitution.
- **Reaction e:** Friedel-Crafts alkylation using tert-butyl chloride and AlCl₃.

**Remember:** 
- Rearrangements can affect the carbon skeleton in some reactions.
- Consider the conditions (hot or cold) to predict the regioisomer formed in a and b.
- Use scratch paper to verify your line structures match the expected major products.
Transcribed Image Text:### Predicting Products in Organic Reactions **Instructions:** Using line structures, give the major product for each of the following reactions. Rearrangements are possible. **Do not show mechanisms here**. Use scratch paper if needed. NR if no reaction; indicate stereochemistry as we have discussed (E = enantiomer; D = diastereomer). #### Reactions: **a.** \[ \text{CH}_3-CH=CH-CH_3 \xrightarrow{\text{HCl, hot}} ? \] **b.** \[ \text{CH}_3-CH=CH-CH_3 \xrightarrow{\text{HCl, cold}} ? \] **c.** ![Benzene ring] \xrightarrow{\text{Br}_2, \text{FeBr}_3} ? \] **d.** ![T-butanol with benzene ring] \xrightarrow{\text{HNO}_3, \text{H}_2\text{SO}_4} ? \] **e.** ![Methoxy benzene] \xrightarrow{\text{tert-butyl chloride, AlCl}_3} ? \] Note: NR is not the answer for any of these reactions. ### Additional Explanation: - **Reaction a and b:** Focuses on the addition of HCl to an alkene. The condition (hot and cold) can impact the product structure. - **Reaction c:** Aromatic bromination using Br₂ and FeBr₃, a common electrophilic aromatic substitution. - **Reaction d:** Nitration using HNO₃ and H₂SO₄, another example of electrophilic aromatic substitution. - **Reaction e:** Friedel-Crafts alkylation using tert-butyl chloride and AlCl₃. **Remember:** - Rearrangements can affect the carbon skeleton in some reactions. - Consider the conditions (hot or cold) to predict the regioisomer formed in a and b. - Use scratch paper to verify your line structures match the expected major products.
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