H* H* COH 1. NaBH4 1. EtMgBr k 2. NH,CI(aq) 2. NH,Cl(aq) H* H2 Pd NH2 I I-Z

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1.
) Predict Products. Using line structures, give the major product.
Rearrangements are possible. DON'T SHOW MECHANISMS HERE. Use scratch paper if
needed. NR if no reaction; indicate stereochemistry as we have discussed
(E=enantiomer; D = Diastereomer)
H*
H*
a
H
HO
1. NaBH4
1. EtMgBr
k
b
2. NH,CI(aq)
2. NH,Cl(aq)
H+
H2
Pd
NH2
H*
SOCI2
m
d.
HO,
HO
H.
„Me
COH
e
1. NABH4
1. LIAIH,
f
2. NH,CI(aq)
2. NH,CI(aq)
1. NABH4
1. LIAIH4
p
g
ОН
2. NH,CI(aq)
2. NH,CI(aq)
1. LIAIH4
1. NaBH4
h
2. NH,CI(aq)
OCH3
2. NH,CI(aq)
1. LIAIH4
P2O5
`NH2
2. NH,Cl(aq)
Transcribed Image Text:1. ) Predict Products. Using line structures, give the major product. Rearrangements are possible. DON'T SHOW MECHANISMS HERE. Use scratch paper if needed. NR if no reaction; indicate stereochemistry as we have discussed (E=enantiomer; D = Diastereomer) H* H* a H HO 1. NaBH4 1. EtMgBr k b 2. NH,CI(aq) 2. NH,Cl(aq) H+ H2 Pd NH2 H* SOCI2 m d. HO, HO H. „Me COH e 1. NABH4 1. LIAIH, f 2. NH,CI(aq) 2. NH,CI(aq) 1. NABH4 1. LIAIH4 p g ОН 2. NH,CI(aq) 2. NH,CI(aq) 1. LIAIH4 1. NaBH4 h 2. NH,CI(aq) OCH3 2. NH,CI(aq) 1. LIAIH4 P2O5 `NH2 2. NH,Cl(aq)
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