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1. Rearrangements are possible. DON'T SHOW MECHANISMS HERE. Use scratch paper if needed. NR if no reaction; indicate stereochemistry as we have discussed Predict Products. Using line structures, give the major product. (E=enantiomer; D = Diastereomer) HO Conc. H2SO4 МСРВА b THE 1. Br2, H,O 2. NaOH, heat OH d 1. Na 2. EtBr MMPP e OH PBR3 f acetone РСС g но CH2CI2 1. NaCN 2. H+ H2SO4 i OH

1. Rearrangements are possible. DON'T SHOW MECHANISMS HERE. Use scratch paper if needed. NR if no reaction; indicate stereochemistry as we have discussed Predict Products. Using line structures, give the major product. (E=enantiomer; D = Diastereomer) HO Conc. H2SO4 МСРВА b THE 1. Br2, H,O 2. NaOH, heat OH d 1. Na 2. EtBr MMPP e OH PBR3 f acetone РСС g но CH2CI2 1. NaCN 2. H+ H2SO4 i OH

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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### Organic Chemistry: Predicting Products **Instructions:** Using line structures, predict the major product of each given reaction. Rearrangement is possible. Do not show mechanisms here. Use scratch paper if needed. If no reaction occurs, indicate with "NR". Indicate stereochemistry as discussed in previous lessons (indicate E=enantiomer; D=diastereomer where applicable). **Reactions:** 1. **a)** Starting Material: ![cyclohexanol](https://via.placeholder.com/20) Reagent: Conc. H₂SO₄ Reaction Scheme: - Reactant: Cyclohexanol - Reagent: Concentrated H₂SO₄ \( \rightarrow \) 2. **b)** Starting Material: ![benzene](https://via.placeholder.com/20) Reagent: MCPBA, THF Reaction Scheme: - Reactant: Cyclohexene - Reagent: MCPBA, Tetrahydrofuran (THF) \( \rightarrow \) 3. **c)** Starting Material: ![2-bromo-2-methylpropane](https://via.placeholder.com/20) Steps: 1. Br₂, H₂O 2. NaOH, heat Reaction Scheme: - Reactant: 2-Methyl-2-butene - Reagents: 1. Bromine in Water (Br₂, H₂O) 2. Sodium Hydroxide, Heat (NaOH, heat) \( \rightarrow \) 4. **d)** Starting Material: ![cyclopentanol](https://via.placeholder.com/20) Steps: 1. Na 2. EtBr Reaction Scheme: - Reactant: Cyclopentanol - Reagents: 1. Sodium (Na) 2. Ethyl Bromide (EtBr) \( \rightarrow \) 5. **e)** Starting Material: ![oxirane](https://via.placeholder.com/20) Reagent: MMPP Reaction Scheme: - Reactant: Cyclopentene oxide - Reagent: Magnesium Monoperoxyphthalate (MMPP) \( \rightarrow
Transcribed Image Text:### Organic Chemistry: Predicting Products **Instructions:** Using line structures, predict the major product of each given reaction. Rearrangement is possible. Do not show mechanisms here. Use scratch paper if needed. If no reaction occurs, indicate with "NR". Indicate stereochemistry as discussed in previous lessons (indicate E=enantiomer; D=diastereomer where applicable). **Reactions:** 1. **a)** Starting Material: ![cyclohexanol](https://via.placeholder.com/20) Reagent: Conc. H₂SO₄ Reaction Scheme: - Reactant: Cyclohexanol - Reagent: Concentrated H₂SO₄ \( \rightarrow \) 2. **b)** Starting Material: ![benzene](https://via.placeholder.com/20) Reagent: MCPBA, THF Reaction Scheme: - Reactant: Cyclohexene - Reagent: MCPBA, Tetrahydrofuran (THF) \( \rightarrow \) 3. **c)** Starting Material: ![2-bromo-2-methylpropane](https://via.placeholder.com/20) Steps: 1. Br₂, H₂O 2. NaOH, heat Reaction Scheme: - Reactant: 2-Methyl-2-butene - Reagents: 1. Bromine in Water (Br₂, H₂O) 2. Sodium Hydroxide, Heat (NaOH, heat) \( \rightarrow \) 4. **d)** Starting Material: ![cyclopentanol](https://via.placeholder.com/20) Steps: 1. Na 2. EtBr Reaction Scheme: - Reactant: Cyclopentanol - Reagents: 1. Sodium (Na) 2. Ethyl Bromide (EtBr) \( \rightarrow \) 5. **e)** Starting Material: ![oxirane](https://via.placeholder.com/20) Reagent: MMPP Reaction Scheme: - Reactant: Cyclopentene oxide - Reagent: Magnesium Monoperoxyphthalate (MMPP) \( \rightarrow
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