1. In the reaction below, chlorine dioxide (CIO2), a reddish-yellow gas that is soluble in water, yields CIO3- and CIO2- ions in a basic solution. In a series of experiments, the following initial rates of disappearance of CIO2 and OH- were obtained. What is the value of the rate constant? 2CIO2 (aq) + 20OH-(aq) → CI03 (aq) + CIO2 (aq) + H20 CIO2 Initial Rate Initial concentrations CIO2 OH- Exp 1 0.680 M 0.256 M 4.0772 M/s Exp 2 0.227 M 0.256 M 0.1506 M/s Exp 3 0.227 M 0.767 M 0.1517 M/s

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1. In the reaction below, chlorine dioxide (CIO2), a reddish-yellow gas that is soluble in water, yields CIO;
and CIO2- ions in a basic solution. In a series of experiments, the following initial rates of disappearance
of CIO2 and OH- were obtained. What is the value of the rate constant?
2CIO2 (aq) + 2OH-(aq) → CIO3- (aq) + CIO2- (aq) + H20
Initial concentrations
CIO2-
CIO2
OH-
Initial Rate
Exp 1 0.680M
0.256 M
4.0772 M/s
Exp 2 0.227 M
0.256 M
0.1506 M/s
Exp 3 0.227 M
0.767 M
0.1517 M/s
Transcribed Image Text:1. In the reaction below, chlorine dioxide (CIO2), a reddish-yellow gas that is soluble in water, yields CIO; and CIO2- ions in a basic solution. In a series of experiments, the following initial rates of disappearance of CIO2 and OH- were obtained. What is the value of the rate constant? 2CIO2 (aq) + 2OH-(aq) → CIO3- (aq) + CIO2- (aq) + H20 Initial concentrations CIO2- CIO2 OH- Initial Rate Exp 1 0.680M 0.256 M 4.0772 M/s Exp 2 0.227 M 0.256 M 0.1506 M/s Exp 3 0.227 M 0.767 M 0.1517 M/s
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