1. Give IUPAC names for the following carboxylic acids: (a) (b) Br (c) CH3 O || CH3CHCH₂COH CH3CHCH₂CH₂COH CO₂H CH3CH₂CHCH₂CH₂CH3

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Assignment 11
1.
Give IUPAC names for the following carboxylic acids:
(a)
(b) Br
(c)
CH3 O
||
||
T
CH3CHCH₂CH₂COH
CH3CHCH₂COH
H
H
H
H
(d)
(c)
(e)
C=C
HO₂C
CO₂H
H3C
CH₂CH₂COH
2.
Give IUPAC names for the following acyl derivatives:
O
(b)
O
(c)
O
(a) CH3
CH3CHCH₂CH₂CCI
.CH2CNH2
CH3CHCOCHCH3
CH3 CH3
(d)
(e)
CH3
O
CHCH3
64
(g)
O
(h)
CH3
H₂C=CHCH₂CH2CNHCH3
CH3CH₂CHCN
3.
Predict the products of the following nucleophilic acyl substitution reactions:
(a)
O
(b)
NaOH
NH3
?
?
H₂O
H3C
OCH3
H3C
CH3NH2
NaOCH3
CH3OH
?
?
H3C
CH3
H3C
SCH3
4.
What products would you obtain by treating benzoic acid with the following
reagents?
(a) SOC12 (b) CH3OH, HC1 (c) LiAlH4 (d) NaOH
5.
How could you prepare the following esters using the reaction of an acid chlo-
ride with an alcohol?
(a) CH3CH₂CO₂CH3 (b) CH3CO2CH2CH3 (c) Cyclohexyl acetate
OCHCH3
CH3
CO₂H
CH3CH₂CHCH₂CH₂CH3
(d)
(f)
5
Transcribed Image Text:Assignment 11 1. Give IUPAC names for the following carboxylic acids: (a) (b) Br (c) CH3 O || || T CH3CHCH₂CH₂COH CH3CHCH₂COH H H H H (d) (c) (e) C=C HO₂C CO₂H H3C CH₂CH₂COH 2. Give IUPAC names for the following acyl derivatives: O (b) O (c) O (a) CH3 CH3CHCH₂CH₂CCI .CH2CNH2 CH3CHCOCHCH3 CH3 CH3 (d) (e) CH3 O CHCH3 64 (g) O (h) CH3 H₂C=CHCH₂CH2CNHCH3 CH3CH₂CHCN 3. Predict the products of the following nucleophilic acyl substitution reactions: (a) O (b) NaOH NH3 ? ? H₂O H3C OCH3 H3C CH3NH2 NaOCH3 CH3OH ? ? H3C CH3 H3C SCH3 4. What products would you obtain by treating benzoic acid with the following reagents? (a) SOC12 (b) CH3OH, HC1 (c) LiAlH4 (d) NaOH 5. How could you prepare the following esters using the reaction of an acid chlo- ride with an alcohol? (a) CH3CH₂CO₂CH3 (b) CH3CO2CH2CH3 (c) Cyclohexyl acetate OCHCH3 CH3 CO₂H CH3CH₂CHCH₂CH₂CH3 (d) (f) 5
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