for the given alkyl position. Bond Dissociation Energies (for A-BA + B) Bond broken AH (kJ/mol) Bond broken AH (kJ/mol) 436 366 193 432 243 H-H Br-Br Cl-Cl H T CH3CHCH3 + Br₂ H I CH3CHCH3 + Cl₂ H-Br H-Cl Br CH3CHCH3 + HBr pare the CI CH3CHCH3 + HCI ΔΗ = ΔΗ = alpy Bond broken (CH3)₂CH-H (CH3)₂CH-Br (CH,),CH–C1 AH (kJ/mol) 413 298 355 kJ/mol kJ/mol
for the given alkyl position. Bond Dissociation Energies (for A-BA + B) Bond broken AH (kJ/mol) Bond broken AH (kJ/mol) 436 366 193 432 243 H-H Br-Br Cl-Cl H T CH3CHCH3 + Br₂ H I CH3CHCH3 + Cl₂ H-Br H-Cl Br CH3CHCH3 + HBr pare the CI CH3CHCH3 + HCI ΔΗ = ΔΗ = alpy Bond broken (CH3)₂CH-H (CH3)₂CH-Br (CH,),CH–C1 AH (kJ/mol) 413 298 355 kJ/mol kJ/mol
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Use the table of bond dissociation energies to calculate and compare the enthalpy of monobromination and monochlorination
for the given alkyl position.
Bond Dissociation Energies (for A-B → A •+•B)
Bond broken AH (kJ/mol) Bond broken
436
193
243
H-H
Br-Br
Cl-Cl
H
CH3CHCH3 + Br₂
H-Br
H-Cl
AH (kJ/mol)
366
432
Br
|
CH3CHCH3 + HBr
H
CH, CHICH
CH3CHCH3 + Cl₂ → CH3CHCH3 + HCI
AH =
AH =
Bond broken
(CH₂)₂CH-H
(CH3)₂CH-Br
(CH3)₂CH-Cl
AH (kJ/mol)
413
298
355
kJ/mol
kJ/mol
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