1. For the reaction A + B D+E the following mechanism was suggestedk1A+ B20k3A +Dk42BEDerive the rate low by applying any inequalities condition you deem appropriate!2. The reaction 3Ce* + Cr*3Ce* + Cr* has an experimentally determinedrate aw given by:d[Cr®* ]= kdt[Cr* ][Ce* J°[Ce* ]exShow that the mechanismkiCe4+ + Cr³+Cr++ + Ce3+k2Ce4+ + Cr+- Cr+ + Ce3+k3Ce+ + Cr*+Cró+ + Ce³+will account for the empirical rate low provided certain inequalities exist and byapplying the steady-state approximation (SSA).

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Answered: 1. For the reaction A + B D+E the…

1. For the reaction A + B D+E the following mechanism was suggested A+ B k2 20 k3 A + D k4 2B E Derive the rate low by applying any inequalities condition you deem appropriate!

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 30E: The reaction 2I-(aq)+S2O82-(aq)I2(aq)+2SO42-(aq) was studied at 25C. The following results were...

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The following experimental data were obtained for the reaction of \'I14* and NOf in acidic solution. NH/(aq) + NO2-(aq) — N;(g) + 2 H,O(f) INH/I (mol L1) [NO21 (mol L-1, Rate = A[NJ/At (mol L-1 s’) 0.0092 0.098 3.33 X IO"7 0.0092 0.049 1.66 X 10‘7 0.0488 0.196 3.51 X 10"6 0.0249 0.196 1.80 X 10-6 Determine the rate law for this reaction and calculate the rate constant.
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