1. For each of the following statements, indicate whether they are true of false. ⚫ the terms primary, secondary and tertiary have different meanings when applied to amines than they do when applied to alcohols. • a tertiary amine is one that is bonded to a tertiary carbon atom (one with three C atoms bonded to it). • simple five-membered heteroaromatic compounds (e.g. pyrrole) are typically more electron rich than benzene. ⚫ simple six-membered heteroaromatic compounds (e.g. pyridine) are typically more electron rich than benzene. • pyrrole is very weakly basic because protonation anywhere on the ring disrupts the aromaticity. • thiophene is more reactive than benzene toward electrophilic aromatic substitution. • pyridine is more reactive than nitrobenzene toward electrophilic aromatic substitution. • the lone pair on the nitrogen atom of pyridine is part of the pi system.

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ChapterU2: Smells: Molecular Structure And Properties
SectionU2.6: Where's The Fun?: Functional Groups
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1. For each of the following statements, indicate whether they are true of false.
⚫ the terms primary, secondary and tertiary have different meanings when applied to amines
than they do when applied to alcohols.
• a tertiary amine is one that is bonded to a tertiary carbon atom (one with three C atoms bonded
to it).
• simple five-membered heteroaromatic compounds (e.g. pyrrole) are typically more electron
rich than benzene.
⚫ simple six-membered heteroaromatic compounds (e.g. pyridine) are typically more electron
rich than benzene.
• pyrrole is very weakly basic because protonation anywhere on the ring disrupts the aromaticity.
• thiophene is more reactive than benzene toward electrophilic aromatic substitution.
• pyridine is more reactive than nitrobenzene toward electrophilic aromatic substitution.
• the lone pair on the nitrogen atom of pyridine is part of the pi system.
Transcribed Image Text:1. For each of the following statements, indicate whether they are true of false. ⚫ the terms primary, secondary and tertiary have different meanings when applied to amines than they do when applied to alcohols. • a tertiary amine is one that is bonded to a tertiary carbon atom (one with three C atoms bonded to it). • simple five-membered heteroaromatic compounds (e.g. pyrrole) are typically more electron rich than benzene. ⚫ simple six-membered heteroaromatic compounds (e.g. pyridine) are typically more electron rich than benzene. • pyrrole is very weakly basic because protonation anywhere on the ring disrupts the aromaticity. • thiophene is more reactive than benzene toward electrophilic aromatic substitution. • pyridine is more reactive than nitrobenzene toward electrophilic aromatic substitution. • the lone pair on the nitrogen atom of pyridine is part of the pi system.
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