Answered: R₁ NaOH, H₂O 'N' K₁ R₁ A ANH NH-O B…

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R₁ NaOH, H₂O 'N' K₁ R₁ A ANH NH-O B NaOH, H₂O K2 R₁ CNH + O

Introduction to General, Organic and Biochemistry

11th Edition

ISBN:9781285869759

Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Chapter4: Chemical Reactions

Section: Chapter Questions

Problem 4.100P

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Question

Amide B hydrolyzes about 100,000 times faster than amide A (k 2 >>k1 ) even tho in same conditions. Please explain why b is faster using resononace structures and if they occur in tetrahedral mechanism .

R₁
NaOH, H₂O
'N'
K₁
R₁
A
ANH
NH-O
B
NaOH, H₂O
K2
R₁
CNH + O

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