44 > Draw the structures of the carboxylic acid and the alcohol that produce the ester shown in an esterification reaction. Include all hydrogen atoms in the structures. carboxylic acid Select Draw Templates More / # C O H CH3 H3C-C H alcohol Submit Answ HCI CH 3 -C-O-CH2-CH3 Erase Select Draw Templates More / # # C 0 H B Q Search Erase

44 > Draw the structures of the carboxylic acid and the alcohol that produce the ester shown in an esterification reaction. Include all hydrogen atoms in the structures. carboxylic acid Select Draw Templates More / # C O H CH3 H3C-C H alcohol Submit Answ HCI CH 3 -C-O-CH2-CH3 Erase Select Draw Templates More / # # C 0 H B Q Search Erase

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter17: Alcohols And Phenols

Section17.SE: Something Extra

Problem 37AP: Give IUPAC names for the following compounds:

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1. NaOEt CO₂Et 2. H3O+ 3. heat Br H3C H₁C CO₂Et CO₂H CO2 + EtOH The malonic ester synthesis is a carbonyl alkylation reaction. It is used to prepare carboxylic acids from primary alkyl halides, lengthening the carbon chain by two atoms. Thus, the product can be visualized as being a "substituted acetic acid." The reaction consists of three steps: generation of the enolate anion followed by SN2 reaction with a primary alkyl halide, ester hydrolysis under acid conditions, and decarboxylation. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions EtO₂C X ¯:0: :0: Br: EtO₂C. Br CH3 H3C CH3 CH3 56
15
Draw the organic product formed in the reaction.
Draw the product of the reaction between a ketone and an alcohol. Include all hydrogen atoms in the product. H₂C + 1 mole equiv. CH3 HỌ-CH2-CH3 H* Draw Templates More ////// C H 0 Select Ć Erase Q2 Q How would you classify the product of the reaction? Note that a hemiacetal formed from a ketone is also called a hemiketal; an acetal formed from a ketone is also called a ketal. The product is a ketone. The product is a hemiketal. The product is an alcohol. The product is a ketal.
Give IUPAC names for the following compounds:
Reaction with which of the following compounds in an acetylide reaction would lengthen the carbon chain by one carbon and add a primary alcohol? O ethanal O formaldehyde О ерохide O acetone O carbonic acid QUESTION 4 The reagent/reaction of choice for this reduction is || HC-CH=CH-CH2CH2CH2 CO2H CH2OH-CH=CH-CH2CH2CH2 CO2H O lithium aluminum hydride O potassium permanganate O sodium borohydride O Grignard reaction O SN2 reaction
1. NaOEt CO₂Et 2. H3O+ 3. heat Br H3C CO₂H CO2 H3C CO₂Et The malonic ester synthesis is a carbonyl alkylation reaction. It is used to prepare carboxylic acids from primary alkyl halides, lengthening the carbon chain by two atoms. Thus, the product can be visualized as being a "substituted acetic acid." The reaction consists of three steps: generation of the enolate anion followed by SN2 reaction with a primary alkyl halide, ester hydrolysis under acid conditions, and decarboxylation. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions 22 CX EtO₂C EtO₂C HOCH2CH3 HOCH2CH3 EtO₂C EtO₂C
Draw the structures of the carboxylic acid and the alcohol that produce the ester shown in an esterification reaction. Include all hydrogen atoms in the structures. 128 4 carboxylic acid Select Draw Templates More R F V |||||| C O H 5 G Search or type URL T G tv B MacBook Pro 6 Y H & 7 N U Erase J * 00 8 M ✪ - H H3C-C C H alcohol CH 3 ( 9 K Select Draw Templates More ///// O < CH3 I O L с 310 command 0 H P V O—CH,–CH3 : ; Aa 4 + " [ option = Erase O } 1 delete
15) Propose a synthetic route to convert 3-methyl-1-butanol into 3-methyl-2-butanol. OH OH A) 1. NaOH; 2. H3O+ B) 1. H₂SO4, heat; 2. NaBH4; 3. H3O+ C) 1. H2SO4, heat; 2. Hg(OAc)2, H2O; 3. NaBH4 D) 1. Hg(OAc)2, H2O; 2. H2SO4, heat; 3. NaBH4 E) 1. NaOMe; 2. BH3-THF; 3. H2O2, NaOH Answer: C
نقطتان )2 Choose the best solvent to the following (Chloroacetic acid) CICH2-C-OH Soluble in ether Not soluble in ether هذا السؤال مطلوب إرسال LAllaa Google lai e 19all 65 Jhl pe beul.okE Google Je lael d9 sall Lia sLail a pl ell la allla ala Google alai
For the following lise ONLY reactions we have studied in cla Powerpoint slides for preparations and reactie you Check your APPS out 6 contpletely different reactions of acetophenone trea b) Write out 3 preparations of 2-methyl-2-butanol, using a different starting material for each one. You may use preps where you just change the functional group, and/or preps where you construct the carbon chain. group ind/o Juc
How would you synthesize the following compounds from butanoic acid using reagents from the table? Use letters from the table to list reagents in the order used (first at the left). Example: ab Reagents 1. NABH4 PB13 j KOH / alcohol a e 2. H3O* b KOTBU 1. LIAIH4 2. H30* k f Mg / dry ether H2/Pt g 1. Li 2. Cul 1. СО2 2. Н,о* HBr, dark no peroxides d h 1-bromobutane 1. ВН3 / THF 2. H2O2 / NaOH i H3O*, heat n NaCN a) 2-methylbutanoic acid b) 1-butene