1 1 V Vapor Liquid Membrane VID Figure P4.69 4.69 A membrane test cell is designed and oper- ates along the lines suggested in Fig. P4.69. A pure liquid is under its own vapor pressure in the closed container below the membrane. The upper volume is initially pumped down to (nearly) zero absolute pressure, after which va- por from the lower compartment dissolves in the membrane and diffuses across the membrane. Assume that both vapor phases are well mixed. Given the membrane area A normal to the diffu- sion flux, the membrane thickness H, the volume V of the upper compartment, and the vapor pres- sure Pvap of the liquid, derive an expression from which you can calculate the product of solubility and diffusivity of the vapor in the membrane, from data on the time tos at which the pressure in the upper compartment rises to the value 0.5pvap. Do not assume that p(t) < Pvap. The goal is to express a DAB in terms of parameters given. a is the partition coefficient between the concentration in membrane and in vapor. i.e. Cmembrane = a Cvapor at the interfaces.
1 1 V Vapor Liquid Membrane VID Figure P4.69 4.69 A membrane test cell is designed and oper- ates along the lines suggested in Fig. P4.69. A pure liquid is under its own vapor pressure in the closed container below the membrane. The upper volume is initially pumped down to (nearly) zero absolute pressure, after which va- por from the lower compartment dissolves in the membrane and diffuses across the membrane. Assume that both vapor phases are well mixed. Given the membrane area A normal to the diffu- sion flux, the membrane thickness H, the volume V of the upper compartment, and the vapor pres- sure Pvap of the liquid, derive an expression from which you can calculate the product of solubility and diffusivity of the vapor in the membrane, from data on the time tos at which the pressure in the upper compartment rises to the value 0.5pvap. Do not assume that p(t) < Pvap. The goal is to express a DAB in terms of parameters given. a is the partition coefficient between the concentration in membrane and in vapor. i.e. Cmembrane = a Cvapor at the interfaces.
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question
Transcribed Image Text:1
1
V
Vapor
Liquid
Membrane
VID
Figure P4.69
4.69 A membrane test cell is designed and oper-
ates along the lines suggested in Fig. P4.69. A
pure liquid is under its own vapor pressure in
the closed container below the membrane. The
upper volume is initially pumped down to
(nearly) zero absolute pressure, after which va-
por from the lower compartment dissolves in the
membrane and diffuses across the membrane.
Assume that both vapor phases are well mixed.
Given the membrane area A normal to the diffu-
sion flux, the membrane thickness H, the volume
V of the upper compartment, and the vapor pres-
sure Pvap of the liquid, derive an expression from
which you can calculate the product of solubility
and diffusivity of the vapor in the membrane,
from data on the time tos at which the pressure in
the upper compartment rises to the value 0.5pvap.
Do not assume that p(t) < Pvap.
The goal is to express a DAB in terms of parameters given. a is the partition coefficient between
the concentration in membrane and in vapor. i.e. Cmembrane = a Cvapor at the interfaces.
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