k1 26.24 Consider a spherical gel bead containing a biocatalyst uniformly distributed within the gel. Within the gel bead, a homogeneous, first-order reaction AD is promoted by the biocatalyst. The gel bead is suspended within water containing a known, constant, dilute concentration of solute A (CAO). a. Define the system, and identify the source and the sink for the mass-transfer process with respect to reactant A. List three reasonable assumptions for this process. Then, using the "shell balance" approach, develop the differential mate- rial balance model for the process in terms of concentration profile CA. State all boundary conditions necessary to com- pletely specify this differential equation. b. The analytical solution for the concentration profile is given by R sinh(r√√k₁/DAB) CA(r) = CAoo r sinh (R√k₁/DAB) What is the total consumption rate of solute A by one single bead in units of μmol A per hour? The bead is 6.0 mm in diameter. The diffusion coefficient of solute A within the gel is 2×106 cm²/s, k₁ is 0.019 s¹, and CA∞o is 0.02 μmole/cm³. Hint: Differentiate the relationship for CA(r) with respect to r, then estimate the flux NA at r = R.

Introduction to Chemical Engineering Thermodynamics
8th Edition
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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Chapter1: Introduction
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Fundamentals of Momentum, Heat and Mass Transfer by james welty

k1
26.24 Consider a spherical gel bead containing a biocatalyst
uniformly distributed within the gel. Within the gel bead, a
homogeneous, first-order reaction AD is promoted by
the biocatalyst. The gel bead is suspended within water
containing a known, constant, dilute concentration of solute
A (CAO).
a. Define the system, and identify the source and the sink for
the mass-transfer process with respect to reactant A. List
three reasonable assumptions for this process. Then, using
the "shell balance" approach, develop the differential mate-
rial balance model for the process in terms of concentration
profile CA. State all boundary conditions necessary to com-
pletely specify this differential equation.
b. The analytical solution for the concentration profile is
given by
R sinh(r√√k₁/DAB)
CA(r)
= CAoo
r sinh (R√k₁/DAB)
What is the total consumption rate of solute A by one
single bead in units of μmol A per hour? The bead is 6.0
mm in diameter. The diffusion coefficient of solute A
within the gel is 2×106 cm²/s, k₁ is 0.019 s¹, and CA∞o is
0.02 μmole/cm³. Hint: Differentiate the relationship for
CA(r) with respect to r, then estimate the flux NA at r = R.
Transcribed Image Text:k1 26.24 Consider a spherical gel bead containing a biocatalyst uniformly distributed within the gel. Within the gel bead, a homogeneous, first-order reaction AD is promoted by the biocatalyst. The gel bead is suspended within water containing a known, constant, dilute concentration of solute A (CAO). a. Define the system, and identify the source and the sink for the mass-transfer process with respect to reactant A. List three reasonable assumptions for this process. Then, using the "shell balance" approach, develop the differential mate- rial balance model for the process in terms of concentration profile CA. State all boundary conditions necessary to com- pletely specify this differential equation. b. The analytical solution for the concentration profile is given by R sinh(r√√k₁/DAB) CA(r) = CAoo r sinh (R√k₁/DAB) What is the total consumption rate of solute A by one single bead in units of μmol A per hour? The bead is 6.0 mm in diameter. The diffusion coefficient of solute A within the gel is 2×106 cm²/s, k₁ is 0.019 s¹, and CA∞o is 0.02 μmole/cm³. Hint: Differentiate the relationship for CA(r) with respect to r, then estimate the flux NA at r = R.
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