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![01-201
Q 18.7: Identify the starting material necessary to carry out the following transformation:
[H3O]
Br2
Br
D
OH
Br](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fdb82fbf3-cb65-421b-aae1-5c9497a11242%2F4f89a128-9eae-4be8-993a-29cab6e9cfc7%2F4dkeagp_processed.jpeg&w=3840&q=75)
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- Two substitution products result from the reaction between 3-chloro-3-methyl-1- butene with sodium acetate (CH3COO – Na +) in acetic acid under SN1. Identify the products.What would be the major product obtained from the reaction of Br2 with 1-butene if the reaction were carried out in the solvent dichloromethane? Draw the molecule.Nomenclature: provide the systematic names or structure of each of the following compounds. Include E/Z/R/S where relevant.
- 12.Use of KMnO, to effect oxidative cleave of the alkene J, C3H16, yields two fragments, one of which is butanoic acid and the other a ketone, Q. When J reacts with one molar equivalent of H-Cl, the alkyl halide K, C3H17CI, is formed. What are the structures of J, J, and Q? Write all the reactions, and show your reasoning.how many structurally isomeric products form in the free radical bromination of hexane?| Exercises 317 9.21 Identify the reactants from which the following molecules were prepared. If an acetal, identify the carbonyl compound and the alcohol; if an imine, identify the carbonyl compound and the amine; if an alcohol, identify the carbonyl compound and the Grignard reagent (red = 0, blue = N): (a) (b) (c)
- Alkynes do not react directly with aqueous acid as do alkenes, but will do so in the presence of mercury(II) sulfate as a Lewis acid catalyst. The reaction occurs with Markovnikov regiochemistry, so the OH group adds to the more highly substituted carbon and the H adds to the less highly substituted carbon. The initial product of the reaction is a vinyl alcohol, also called an enol. The enol immediately rearranges to a more stable ketone via tautomerization. Draw curved arrows to show the movement of electrons in this step of the mechanism. Arrow-pushing Instructions -X티 Hö: H-O -CH3 -CH3 H30*What is the function of CH2Cl2 in the bromination reactions? Why can it fulfil this rolecomplete the synthetic scheme
- Name the major organic product when we combine 1-propylmagnesium bromide with water.Possible alternative brominations include: Veratrole (1,2-dimethoxybenzene) to 1,2-dibromo-4,5-dimethoxybenzene; 4-Methylacetanilide to 2-bromo-4-methylacetanilide; 2-Methylacetanilide (made in experiment S.1) to 4-bromo-2-methylacetanilide; Vanillin to 5-bromovanillin; Acetanilide to 4-bromoacetanilide; a. b. C. d. e. EXPERIMENT S4: BROMINATION OF AROMATIC COMPOUNDS Certain other acetanilides made in experiment S.1 may also be used as precursors in this experiment. Estimated time: 1 afternoon Associated learning goals: Section 6, LG 6.6; Section 7, LG 7.2 and 7.4 Pre-lab report: complete the standard report form, and answer the following questions. In this experiment, molecular bromine (Br2) is generated from the redox reaction of potassium bromate with hydrobromic acid. Write a balanced equation for this process. Briefly outline the mechanism by which Br2 brominates your aromatic compound. Why do the bromine atoms end up at the positions indicated rather than anywhere else in the…Provide the major organic product of the following reaction. + { A1C13
