. Write out the steps from glucose to the formation of the phospholipid, phosphatidylcholine, using chemical structures for the main substrates in each steps (not things like ATP). If there is a more than one way to do it, only show one way.
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1. Write out the steps from glucose to the formation of the phospholipid, phosphatidylcholine, using chemical structures for the main substrates in each steps (not things like ATP). If there is a more than one way to do it, only show one way.
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- 1. Draw the structure of triglyceride containing the fatty acids palmitic, oleic, and linoleic. How many Hydrogen atoms are needed in the its catalytic hydrogenation? 2. Draw the structure of Phosphatidylserine that contains oleic and arachidonic acid. What role does it play in the cell?6. What is a glycosyltransferase? Choose all that apply Group of answer choices Catalyzes the formation of a bond between a sugar and an amino acid An enzyme that cleaves a glycosidic bond An enzyme that catalyzes the formation of a glycosidic bond An enzyme that transfers nucleotide-sugars from the cytoplasm 7. Which statement(s) is/are true about inverting and retaining glycosyltransferases? a. Inverting glycosyltransferase catalyzes the epimerization of a sugar b. Inverting glycosyltransferase alters the anomeric configuration of the glycosyl donor c. Retaining glycosyltransferase never preserves the anomeric configuration of the glycosyl donor d. Inverting glycosyltransferase switch the order of acceptor and donor. e. An SN1 reaction mechanism results in exclusive retention of stereochemistry of the anomeric carbon6. The lens of the eye is the light refracting medium of the eye, and it has no mitochondria. Glucose is used as an energy source in the lens. Which metabolic pathway of glucose supplics energy to the crystalline eye lens? To answer the question: a) write a diagram of the metabolic pathway that provides the eye's lens with ATP, specify enzymes and coenzymes; b) mark the reactions associated with the ATP consumption and synthesis, calculate the ATP yield during the process; c) specify the mechanisms of ATP synthesis in the process; d) name the tissues and cells in which the ATP synthesis is the same as in the lens; e) write the dehydrogenation reaction and the reaction of final product formation occurring in the process; 6.3. Gluconeogenesis. Regulation of Glycolysis and Gluconeogenesis 271 ) indicate the fate of the end product of the process and the consequences of its accumulation.
- 10. Oxidative Phosphorylation; a. Occurs in which organelle of the cell and in what structure of this organelle? b. Write the names of the enzyme complexes.1. Flip-Flop is considered the LEAST likely to happen of the four membrane movements because it is the LEAST energetically favorable movement of a single fatty acid. For this question DRAW the action of a one phopholipid being flipped from outside facing plasma membrane, to the inside facing plasma membrane. On your drawing put an X near areas of the phospholipids that do NOT want to interact during this process.2. What is the chemical reaction that lactase catalyzes? Write it below in word form as well as in its chemical equation.
- 6. The lens of the eye si the light refracting medium of the eye, and ti has no mitochondria. Glucose is used sa an energy source ni the lens. Which metabolic pathway of glucose supplies energy to the crystalline eye lens? To answer the question: a) write a diagram of the metabolic pathway that provides the eye's lens with ATP, specify enzymes and coenzymes; b) mark the reactions associated with the ATP consumption and synthesis, calculate the ATP yield during the process; )c specify the mechanisms ofATP synthesis ni the process; d)name the tissues and cells in which the ATP synthesis is the same as in hte lens; e) writethe dehydrogenation reaction and the reactionoffinal product formation occurring in the process;Which pathway is shown below? 1. ATP phosphorylates glucose to glucose 6-phosphate. 2. Glucose 6-phosphate isomerizes to fructose 6-phosphate 3. ATP phosphorylation fructose 6-phosphate to fructose 1,6-bisphosphate. EMP Stage 1: Glucose 2 G3P CH,OH CH,OH C-0 CHOPO 4-5. Cleavage produced GP and DHAP which isomerizes to another 3 НО" HO! hexokinase 0-Glucose HO Dihydroxyacetone phosphate (DHAP) Choose one: CH,OPO HO- phosphogucose isomerase OH a-Glucose 6-phosphate OH phosphofructokinase OH CH₂O CH₂OH PO POCHO ADP OH OH a-Fructose 6-phosphate ATP OH OH CHOPO B-Fructose 1,6-bisphosphate AHOTON CHLOPO Glyceraldehyde 3-phosphate (G3P) O A. TCA cycle OB. Glycolysis O C. Fermentation OD. Aromatic catabolism EMP Stage 2:2 G3P 2 Pyruvate Citycoraldehyde phosphate ROSTO krise H-C-DH olaca 1,3-Bisphosphoglycerate NAD P phphucerade COPD. M CH-OPO KH HC OH erpolise ADP 3-Phosphoglycerate H piruvato ise ATP CHOPO CD, H-COPO, CH₂OH 2-Phosphoglycerate + H com C-O H.O CO, CHOPO H₂C Phosphoenolpyruvate…4. Glucose containing 4Catoms was added to isolated hepatocytes in an experiment. Ifthe glucose was added in excess, the rate of triacylglycerol synthesis increased. The determination of carbon atoms in the triacylglycerol molecule confirmed that all carbon atoms in glycerol and fatty acids were "C atoms. Explain the results of the experiment. For that: a) name the mectabolites required for triacylglycerol synthesis, which are produced by glucose catabolism; b) draw the scheme of glucose catabolism to metabolites required for triacylglycerol synthesis which would explain the appearance of 4C atoms in the triacylglycerol molecule; c) draw the scheme representing the conversion of extra glucose to triacylglycerols in the liver.
- II. ILLUSTRATIONS For each of the given proteins: ● Draw the final location of the following proteins after being translocated. ● Label the organelle (as well as the organelle parts/compartments) and the cytosol (if necessary) in order to clearly depict the protein's location and orientation. Label the amino and carboxyl ends of the protein. Below your drawing, indicate: a. the receptor/s b. the energy source C. if there is signal peptide cleavage or none ●3. In muscle cells, the AG for glucose+ ATP 2 glucose – 6-P+ADP is –33.5 kJ mol-1. In contrast, the AG for glucose – 6 – P fructose – 6 – P is -2.5 kJ · mol-1. (a) In a physiological context, which reaction is faster? How do you know? (b) The enzyme that catalyzes glucose + ATP 2 glucose - 6 – P + ADP (hexokinase) is an important point of regulation in glycolysis, while the enzyme that catalyzes glucose – 6 – P2 fructose – 6 – P (phosphoglucose isomerase) is not. Why is hexokinase a good step at which to regulate glycolysis relative to phosphoglucose isomerase?1. Outline the first round of lipid catabolism using a C18 saturated fatty acid. Indicate cofactors and type of chemistry that takes place. a. How much NADH, FADH2 and ACCOA are you getting from complete catabolism of this fatty acid? b. How many moles of ATP are you getting from the breakdown of this fatty acid? Keep in mind that in the mitochondria 1 mole FADH2 gives about 1.5 moles of ATP while 1 mole NADH yields about 2.5 moles of ATP.
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