21st Lecture

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University of Houston *

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3336

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Electrical Engineering

Date

Nov 24, 2024

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pdf

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Uploaded by samirhoballah

Exam 2 mean 53 100 65 A Hish 95 64 48 B LOW 23 47 39 C Geranyl diphosphate substrate fo Plant terpenes kno o 8 Zero E o E 8 O_O O_O o_O to 0 dimethyl ally isopentenyl pyrophosphate b pyrophosphate k vx o E o.io E O_O 00 Geranial pyrophosphate Terpene Biosynthesis J Allylic transposition La I o l Lif i f f P p o O_O O_0 I I 00 O_O o p o D O

ms 0 of O l b 06 o_O w y v I so 00 b o DEE o fo b te H limonene IF Camphor ooppymg camphor I o Ppmg IET T H p pinene H I

it ht o H Sabinene it e OH nor born I cation TO Eko B Holte Holte 350 times BV KOAC KOHL faste endo exo endo Bu is toward longer bridge exo Br toward one earbon bridge Hyper conjugation Bu

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i E e 4 nonclassical carbonium ion 3 center 2 electron bond 13 lactam Antibiotics R a r cHuPh Zo Penicillin G R cHu0Ph Gt3 Penicillin V R k 0 Oxacillin Ph cephalosporins p Excite RIN p R euro'Eetts core Keflin

R Ho Et Fates a Hs Moxon Pencil 1 n 1928 Alexander Fleming a motel Penicillium Genus caused bacteria to undergo sis 19 only small amounts available Oxford ploliceman treated with penicillen isolated from urine of another patient who had been treated 1942 Yule t Mayo Clinic first clinical trial cephalosporins 1948 fungus found near a sewer outlet Sardinian coast

mechanism of action Transpepticlation mech NAM XING NAM NAG 1 I 21719 Ala D Glee D Glu Lys Gly Gly Gly Gly Gly Lys Glyn i l Darla Data D Ala EDAler NAM NAG NAM NAG a Trans Ala cross Dein peptidase D GM I I Lys Enzyme Lys 0000 D Ala f Dftta Data cart Enzyme i oe Chain DAWAH Peptide chain H Cross link o_O

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it TO TE't n t So blocked eell wall biosynthesis Classes of Blactams If it III RTM Is Ht conto cont Penum cavbape.name it R fro Ry ts TT b N 1 NI EN o o echt conH mono oxapenam penem baetan it it R F x s eephem N I e carbecephem could o oxacephen B laelanase Resistance to B lactams O H R

11 2 N qEX 7 0 O 7 0 OH seu OH OH Sev 1 1 Gram Positive Bacteria Positive to Gram stain Purple Thiek cell wall peptidoglycan Gram Negative easier to treat Features of cephalosporins selectivity B lactamase bp it t.tcissteueoeesheeT.eu rs s d's IN effects b o T.tt R stability Of corer metabolic move electrophilic used for than most prodrug m development

MRSA methicillin resistant staphylococcus aureus me H go it FEI neo O F 0 OH Bacteriostat c OH o YA no 0 Tetracyclines h it Theft 1 OH Inhibit Protein Biosynthesis Ribosome a chloramphenicol I et protein ly H o synthesis O_O

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Erythromycin Maeroeycles O.CH 3 CHS OH ftp koHhf cHsg qCHqf vOSusHSo oSuyOClt3

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