Enthalpy of Neutralization Notebook
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Enthalpy of Neutralization
Jing Maniaci
14
th
November 2023
Results:
Part A: Neutralization of 1.00 M HCl with 1.00 M NaOH
Trial 1
Trial 2
Total volume after
mixing
100.39
100.22
T
initial
22.5
22.7
T
final
30.1
30.2
Δ
T
7.6
7.5
Part B: Neutralization of 0.500 M HCl with 0.500 M NaOH
Trial 1
Trial 2
Total volume after mixing
100.27
100.18
T
initial
22.8
22.9
T
final
26.7
26.4
Δ
T
3.9
3.5
Part A
(1.00 M HCl and
1.00 M NaOH)
Part B
(0.500 M HCl
and 0.500 M
NaOH)
Trial 1
Trial 2
Trial 1
Trial 2
Δ
T at mixing
7.6
7.5
3.9
3.5
Mass of calorimeter, empty
27.32g
28.35
28.38
28.57
Mass of calorimeter, full
127.71
128.57
128.65
128.75
Mass of resulting solution
100.39
100.22
100.27
100.18
q
solution
3.189 kJ
3.141 kJ
1.635 kJ
1.466 kJ
q
reaction
-3.189
-3.141
-1.635
-1.466
Δ
H
neutralization
-3.189
-3.141
-1.635
-1.466
Moles of HCl reacted
0.05 moles
0.025 moles
molar
Δ
H
neutralization
-63.78
-62.82
-65.4
-58.64
Average molar
Δ
H
neutralization
-63.3
-62.02
Overall average molar
Δ
H
neutralization
-62.66
Difference between two
average molar
Δ
H
neutralization
-1.28
Percent difference between
two average molar
Δ
H
neutralization
2.04
Calculations for Trial 1:
Δ
T at mixing:
T
final
- T
initial
30.1 – 22.5 = 7.6
Mass of calorimeter, empty
27.32g
Mass of calorimeter, full
127.71g
Mass of resulting solution:
Mass of calorimeter, full – Mass of calorimeter, empty
127.71 – 27.32 = 100.39g
q
solution
:
=
mcΔT
= 100.39g * 4.18 J/(g°C) * 7.6°C
=
3.189 kJ
q
reaction
:
=
- q
solution
=
-3.189
Δ
H
neutralization
:
=
-q
reaction
= -3.189
Moles of HCl reacted:
0.05 moles
molar
Δ
H
neutralization
:
q
reaction
/moles of HCL reacted
-3.189/0.05 = -63.78
Average molar
Δ
H
neutralization
:
(Trial 1 molar
Δ
H
neutralization
+ Trial 2 molar
Δ
H
neutralization
) / 2
= (
-63.78 + -62.82) / 2 = -63.3
Overall average molar
Δ
H
neutralization
:
(Part A Average molar
Δ
H
neutralization
+ Part B Average molar
Δ
H
neutralization
) / 2
= (-63.3 + -62.02) / 2
= -62.66
Difference between two average molar
Δ
H
neutralization
:
(Part A Average molar
Δ
H
neutralization
- Part B
Average molar
Δ
H
neutralization
)
= -63.3 - -62.02
= -1.28
Percent difference between two average molar
Δ
H
neutralization
:
(Difference between two average molar
Δ
H
neutralization
/ Overall average molar
Δ
H
neutralization
) * 100
= (-1.28 / -62.66) * 100
= 2.04 %
Conclusion:
In this lab, the average molar ΔH
neutralization
for Part A was -63.3 kJ/mol; for Part B,
it was -62.02 kJ/mol. The overall average molar ΔH
neutralization
came out to be -62.66
kJ/mol. The percent difference between the two average molar ΔH
neutralization
was 2.04%.
Two areas in the procedure that could have affected our results for the average molar
ΔH
neutralization
were in step 6 we did not rinse the calorimeter, thermometer, and stirrer with
deionized water and wipe them dry before repeating steps 3 through 5 for Trial 2. This
could make the weight higher than what it was and maybe alter the temperature if there
were excess HCL or NaOH on the materials. Another possible source of error that
happened was we did not wait the full five minutes to have the thermometer reading
system stabilize to record the initial temperature reading. Overall this lab went pretty well
and the main takeaway for this lab was to find the effect of the concentrations of the
reactants on the heat and molar heat of neutralization.
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ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
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Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY