SCH4U Lee 1.6

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OCV Chemistry, Grade 12 University Preparation (SCH4U) Ottawa-Carleton Virtual Secondary School 2020-2021 Mr. Daniel Cho-En Lee ( daniel.cho-en.lee@ocdsb.ca ) In terms of orderliness, solids are somewhere between perfectly ordered (crystalline, such as diamond) and totally chaotic (amorphous, such as glass). Of course, the reality is somewhere in between. For simplicity in high school, we only discuss crystalline solids. There are four categories of crystalline solids. (1) Metallic solids = metals Metals are hard, malleable (can be hammered into a sheet, a cube...), and ductile (can be stretched into a wire). Many have melting points > 1000°C, which is in the range of ionic compounds. Indeed, there is something ionic (attraction between full opposite charges) going on in metals. Many metals have loosely associated valence electrons. These negatively-charged valence electrons jump freely from one atom to the next, acting as a “glue” that holds the positively charged nuclei together. The loose and jumpy electrons also explain the good conductivity of electricity and heat. (heat = kinetic energy of particles) Watch: What are metallic bonds? https://www.youtube.com/watch?time_continue=1&v=S08qdOTd0w0& Exercise 1 . The tendency to lose valence electrons gives rise to metal’s conductivity. (a) Which metal conducts electricity more easily, Cu vs. Zn? Why? Cu: [Ar] 4s 1 3d 10 Zn: [Ar] 4s 2 3d 10 Copper has a loose 4s 1 electron (b) Based on your answer in (a), predict whether Ag and Au is a good conductor of electricity and heat. Ag: [Kr] 5s 1 4d 10 Au: [Xe] 6s 1 4f 14 5d 10 (c) Which metal has a higher melting point, Au or Hg? Why? Hg: [Xe] 6s 2 4f 14 5d 10 (d) Why is Hg a liquid at room temperature? 1
OCV Chemistry, Grade 12 University Preparation (SCH4U) Ottawa-Carleton Virtual Secondary School 2020-2021 Mr. Daniel Cho-En Lee ( daniel.cho-en.lee@ocdsb.ca ) (2) Ionic solids = salts Salts are hard as ions are stacked by ionic bonds. However, salts are not malleable and ductile - the opposite, in fact. If we hammer a salt crystal, it will shatter. In the crystal lattice of cations and anions, each cation is surrounded by anions and each anion is surrounded by cations. An external force may shift the alignments of ions, so that cations and cations come into contact, and anions and anions become neighbours. The exact opposite of ionic bond takes place - the strong electrostatic repulsion instantly breaks the lattice. Ionic salts are brittle. Salts do not conduct electricity because the charged ions are not mobile in the lattice. Once they are dissolved in water, ions may move around and sustains an electric current (unit 5). Exercise 2. Draw a Vann diagram to compare metallic solids and ionic solids. Example: Answer: https://docs.google.com/presentation/d/1bWm56zyPZu05reCBTw1ws_6SDfv-Oul19r4EA7JDntQ/edit?usp=sharing (3) Covalent Network (e.g. diamond, rock, graphite, graphene, wood, plastics) Covalent bonds can also build up hard solids. For example, diamond is entirely carbon atoms. Each C atom is covalently bonded to four C in sp 3 bond hybridization, forming the characteristic tetrahedral shape. Rocks are primarily a covalent network of Si n O 2n with various salt ions in the mix. 2
OCV Chemistry, Grade 12 University Preparation (SCH4U) Ottawa-Carleton Virtual Secondary School 2020-2021 Mr. Daniel Cho-En Lee ( daniel.cho-en.lee@ocdsb.ca ) Each Si is connected to four O atoms in sp 3 bond hybridization, while each O is bonded to two Si. The tightly packed covalent bonds make diamond and rocks particularly hard. Another covalent network solid made of carbon is graphite. Unlike diamond, each C atom of graphite is bonded to only three other C in sp 2 hybridization. Since all atoms of sp 2 are on the same plane, graphite is a stack of sp 2 carbon sheets. Recall that sp 2 hybridized carbon, such as C 2 H 4 (ethene), has π bonds both above and below the plane. Numerous π bonds of graphite become a sea of electrons above and below the sheet. Lacking strength in the vertical direction (only LDF between π electron clouds), graphite sheets break apart easily. This is why graphite is the main ingredient of pencil “lead.” The sea of π electrons also enables graphite to conduct electricity. 3
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OCV Chemistry, Grade 12 University Preparation (SCH4U) Ottawa-Carleton Virtual Secondary School 2020-2021 Mr. Daniel Cho-En Lee ( daniel.cho-en.lee@ocdsb.ca ) A single layer of graphite is called graphene . It is a promising nano-material that is tough at the atomic level (a full layer of sp 2 carbon). Graphene also conducts electricity. Wood and plastic are organic compounds, which will be covered in the next unit. Exercise 3 . Is diamond malleable and ductile like metals? Explain why (not). The sp 3 carbon’s covalent network locks each carbon atom in the space. So diamond is not malleable or ductile. Extended topics Scishow: Fullerene https://www.youtube.com/watch?v=4z8Q0aUKuUU Verge science: Why graphene hasn’t taken over the world...yet https://www.youtube.com/watch?v=IesIsKMjB4Y Veritasium: How Does a Transistor Work? https://www.youtube.com/watch?v=IcrBqCFLHIY (4) Molecular solids = individual molecules held together by intermolecular forces (e.g. ice) There are also solids held together by intermolecular forces only. For example, ice consists of individual water molecules held together by hydrogen bonds. This type of solid is confusingly called “molecular solid.” Review: Four types of solids Exercise 4 . On the kitchen counter is a sugar (sucrose) cube and a table salt cube. What type of solids are they? Explain why or why not they are good conductors of electricity. 4
OCV Chemistry, Grade 12 University Preparation (SCH4U) Ottawa-Carleton Virtual Secondary School 2020-2021 Mr. Daniel Cho-En Lee ( daniel.cho-en.lee@ocdsb.ca ) Table salt: ionic solid (held together by ionic bonds) Sugar: molecular solid (held together by hydrogen bonds) Both bad (as solids) Kahoot game! More possible journal topics X-ray crystallography X-ray baggage scanner X-ray CT scan Nuclear fission or fusion power Mass spectroscopy Infrared spectroscopy Radioisotope in medical imaging Magnetic resonance imaging (MRI) - not recommended (too many existing products) Positron emission tomography (PET) scan Additional practices (unit 1 review) There are multiple correct answers. 1. [ ] Which of the following elements or ions are stable? a) 1s 2 b) 1s 2 2s 1 c) 1s 2 2s 2 2p 5 d) [Ne] 3s 2 3p 6 e) [Kr] f) [Xe] 6s 2 4f 14 5d 10 6p 6 adef 2. [ ] Which of the following central atoms are sp 3 hybridized? a) H 2 O b) S F 6 c) C H 4 d) B F 3 e) N H 3 f) C O 2 ace 3. [ ] Which of the following molecules are trigonal planar? a) methane b) carbon atoms in graphene c) carbon atoms in diamond 5
OCV Chemistry, Grade 12 University Preparation (SCH4U) Ottawa-Carleton Virtual Secondary School 2020-2021 Mr. Daniel Cho-En Lee ( daniel.cho-en.lee@ocdsb.ca ) d) water e) NH 3 f) C 2 H 4 bf 4. [ ] Which of these molecules are attracted to each other by hydrogen bonds? a) CO 2 b) CH 4 c) H 2 d) NH 3 e) CHCl 3 f) H 2 O df 5. Why is MgO not soluble in water? The ΔEN of MgO is (3.5-1.2=2.3) is high and the cations and anions carry 2 charges. The electrostatic attractions within the crystal lattice of MgO are much stronger than the ion-dipole attractions between the ions and water. 6. Why does CO 2 become dry ice (solid) at -80ºC, while O 2 and CH 4 are still gases at -100ºC? The O atoms of CO 2 are δ - while the C atom is δ + . The partially positively-charged C of one CO 2 molecule may attract the partially negatively-charged O on another CO 2 molecule. Therefore, there are enough permanent dp-dp interactions among CO 2 molecules to solidify at this temperature. There are only much-weaker induced transient dp- dp interactions among O 2 molecules and among CH 4 molecules. 7. The boiling points of CF 4 , CCl 4 , CBr 4 , and CI 4 are: -128ºC, 77ºC, 190ºC, and 329ºC, respectively. With knowledge of atomic size (which is positively correlated to the number of electrons), provide a hypothesis that explains this upward boiling point trend. Large atom = many electron clouds = lots of chance for uneven distribution of electrons = stronger London Dispersion Force (LDF or induced transient dp-dp) 8. The boiling points of CH 3 Cl, CH 2 Cl 2 , and CHCl 3 , are: -24ºC, 40ºC, and 61ºC, respectively. The boiling point of CCl 4 is 77ºC. Why is that CCl 4 , a “non-polar” compound, having a higher boiling point than “polar” compounds CH 3 Cl, CH 2 Cl 2 , and CHCl 3 ? Cl is much larger than H - has much more electron clouds - there are much stronger transient charges to induce dp- dp interactions among molecules. Stronger LDF! Coverage of Quiz #3 (1.1-1.6) ends Quiz #3 from SCH4U-06 https://docs.google.com/document/d/19WsGFQz7jZHcBKZI7jjnPf0Huj0dW-tYjdOZJ0Pf58M/edit?usp=sharing 6
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OCV Chemistry, Grade 12 University Preparation (SCH4U) Ottawa-Carleton Virtual Secondary School 2020-2021 Mr. Daniel Cho-En Lee ( daniel.cho-en.lee@ocdsb.ca ) 7