Test3

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Palo Alto College *

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Chemistry

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Feb 20, 2024

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Name:________________________ Note: For all problems, Kw will always be 1.0 x 10 -14 (10 pts) 1. In the following reactions, complete the reaction and identify the acid the base, conjugate acid and conjugate base A. NaOH(aq) + H 2 O(l) Acid: Base: Conj. Acid: Conj. Base: B. HCl(aq) + H 2 O(l) Acid: Base: Conj. Acid: Conj. Base: C. CH 3 COO - (aq) + HCl(aq) Acid: Base: Conj. Acid: Conj. Base D. CH 3 COOH(aq) + KOH(aq) Acid: Base: Conj. Acid: Conj. Base E.CH 3 NH 3 (aq) + CH 3 NH 2 - (aq) Acid: Base: Conj. Acid: Conj. Base (5 pts) 2. What is the difference between a strong acid and weak acid? Which one has a higher Ka value? (5 pts) 3. If [H 3 O + ] is 7.25 x 10 -8 , what is the concentration of OH - ? Is this solution acidic or basic?
4. You are working with a 25.0 L solution that contains 2.5 M weak acid (HA). The Ka of HA is 4.52 x 10 -6 . (5) A. What is the Kb of the conjugate base? (10) B. What is the pH of this solution? (5)C. What is the percent ionization of HA?
(3 pts) 5. Circle the strongest acid H 2 O H 2 S H 2 Se H 2 Te (3 pts) 6. Circle the strongest acid HClO 4 HClO 3 HClO 2 HClO (2 pts) 7. Circle the strongest acid H 2 SO 4 HSO 4 - SO 4 2- (7 pts) 8. Circle all combinations below that are buffers NaOH/HCl H 3 O + /OH - CH 3 COOH/CH 3 COO - KOH/NaOH C 2 H 5 NO 2 /C 2 H 4 NO 2 - C 9 H 11 NO 2 /C 9 H 10 NO 2 - FeCl/FeCl 2 (10 pts) 9. A buffer contains 0.250 M of Acid(HA) and 0.175 M of conjugate Base (A - ). The Ka of the acid is 4.23 x 10 -5 . What is the pH of this solution?
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10. You are titrating 20.0 mL 0.250 M HCl (strong acid) with a strong base (0.125 M NaOH). (5 pts) A. What is the pH before the addition of any NaOH (2.5 pts) B. How much NaOH must you add to reach the equivalence point? (2.5 pts) C. What is the pH at the equivalence point? (10 pts) D. What is the pH if you add 5 mL of NaOH past the equivalence point?
(5 pts).11 Instead of HCl in question 10, if you had a weak acid with a Ka = 1.5 x 10 -5 , would the pH be higher, lower, or the same at the equivalence point (compare to your answer in question 10C). Please provide an explanation. (5 pts). 12.The compound AgCl 2 is insoluble in water. This compound has a Ksp = 2.54 x 10 -18 . What is the molar solubility of this compound? (5 pts). 13. If, in question 12, there was already 2.5 x 10 -4 M of Cl dissolved in the solution, would the molar solubility of AgCl 2 : increase, decrease, or stay the same. Explain below.
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Equation Sheet K w = ¿ | pH =− log ¿ | pH + pOH = 14.00 | p K a =− log K a | percent ionization = ¿¿¿ | K a K b = K w | p K a + pK b = 14 | pH = p K a + log [ base ] [ acid ]