exam 1 Ch223 2024 Spring (1)

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University of South Alabama *

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CH 465

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Chemistry

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Feb 20, 2024

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Exam 1 Quantitative Analysis Fall 2024 Name:__________________________ CWID:______________________ 1. 2. μ = x ± N 3. 1 Q critical values for rejection quotient Q
There is only one correct answer to each question below (5 points for each question) 1. Find the number of K +  ions in 5.08 mol of K 2 HPO 4 (Avogadro constant NA=6.02 10 23 /mol). A. 2.11 10 20 B. 1.19 10 15 C. 6.12 10 24 D. 8.35 10 12 2. What is the millimoles of solute in 650 mL of 3.75 10 -3 M KSCN aqueous solution? A. 8.56 millimoles B. 2.44 millimoles C. 1.83 millimoles D. 2.83 millimoles 3. What are the millimoles of solute in 6.80 L of a solution that contains 7.27 ppm of CuSO 4 (MM=159.6086 g/mol) aqueous solution (density = 1.0 g/mL)? A. 1.23 10 -3 millimoles B. 1.93 10 -1 millimoles C. 2.44 10 -6 millimoles D. 3.10 10 -1 millimoles 4. What is the mass in milligrams of solute in 185.0 mL of 0.660 M sucrose (MM=342 g/mol)? A. 9.12 10 3 mg B. 4.18 10 4 mg C. 2.45 10 6 mg D. 7.75 10 4 mg 5. Calculate the molar H 3 O +  ion concentration of a solution that has a pH of 4.24. A. 6.1 10 -5 M B. 4.8 10 -5 M C. 5.8 10 -5 M D. 3.2 10 -5 M 6. Calculate the p-functions for Br - in a solution that is 0.00670 M in NaBr. A. 2.233 B. 7.093 C. 5.899 D. 2.174 7. A 16.89 % (w/w) Fe(NO 3 ) 3 (241.86 g/mol) solution has a density of 1.063 g/mL. Calculate the molar analytical concentration of Fe(NO 3 ) 3 in this solution. A. 3.223 M B. 8.976 M C. 0.741 M D. 2.134 M 8. A 18.0 % (w/w) NiCl 2 (129.61 g/mol) solution has a density of 1.143 g/mL. Calculate the molar concentration of Cl - ions in the solution. A. 0.13 M B. 4.55 M C. 2.57 M 2
D. 3.17 M 9. Describe the preparation of 650 mL of 5.40 M H 3 PO 4 (MM= 97.995181 g/mol) from the commercial reagent that is 86% H 3 PO 4 (w/w) and has a specific gravity of 1.71. A. Take 189 mL of the concentrated reagent and dilute to 650 mL with water B. Take 234 mL of the concentrated reagent and dilute to 650 mL with water C. Take 134 mL of the concentrated reagent and dilute it to 650 mL with water D. Take 331 mL of the concentrated reagent and dilute it to 650 mL with water 10. What mass of solid La(IO 3 ) 3 (663.6 g/mol) is formed when 51.0 mL of 0.230 M La 3+ are mixed with 72.0 mL of 0.526 M IO 3 - ? A. 3.89 g B. 7.78 g C. 2.23 g D. 5.77 g 11. The 95% confidence limits (CL) for ppm magnesium in a sample are 3.56 ± 0.32 ppm Mg, this indicates that the interval of 3.24 ppm Mg ~ 3.88 ppm Mg A. has a 95 % chance of enclosing the experimental mean B. has a 95 % chance of enclosing the true value of ppm Mg in the sample C. enclose 95 % of the measured data points D. has a 95 % chance of finding the standard deviation 12. According to the following reaction, how many grams of sulfur (32.06 g/mol) are formed when 16.4 g of water (18.01528 g/mol) are formed? 2H 2 S(g) + SO 2 (g) → 3 S(s) + 2H 2 O(l) A. 24.3 g B. 56.1 g C. 43.8 g D. 46.4 g 13. Give the theoretical yield , in moles, of CO 2 from the reaction of 4.00 moles of C 8 H 18 with 4.00 moles of O 2 . 2 C 8 H 18 + 25 O 2 → 16 CO 2 + 18 H 2 O A. 1.12 B. 1.64 C. 2.56 D. 3.45 14. Which is NOT an option to detect systematic error? A. Analyzing Standard Samples B. Using an Independent Analytical Method C. Increase the number of replicates of the measurement D. Performing Blank Determinations 15. Determination of phosphorus in blood serum gave results of 4.40, 4.43, 4.64 , 4.48, and 4.49 ppm P. Determine whether the 4.64 ppm result is an outlier or should be retained at the 99% confidence level. A. Q exp =0.63, Q Crit =0.821, Decision=Retain B. Q exp =0.44, Q Crit =0.832, Decision=Reject C. Q exp =0.63, Q Crit =0.832, Decision=Retain D. Q exp =0.34, Q Crit =0.821, Decision=Reject 3
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16. An atomic absorption method for the determination of copper in fuel samples yielded a pooled standard deviation of s=0.26 ug Cu/mL ( s= ). The analysis of oil from a reciprocating aircraft engine showed a copper content of 7.60 ug Cu/mL. Calculate the 95 % confidence intervals for the result if it was based on the mean of 4 analyses. A. Confidence interval = 7.60 0.32 B. Confidence interval = 7.60 0.28 C. Confidence interval = 7.60 0.25 D. Confidence interval = 7.60 0.77 17. A chemist obtained the following data for percent lindane in the triplicate analysis of an insecticide preparation: 7.23, 6.95, and 7.53. Calculate the 95% confidence interval for the mean of the three data, assuming that the only information about the precision of the method is the precision for the three data. Note: s=0.29 and s≠σ A. Confidence interval = 7.24 0.72 B. Confidence interval = 7.24 0.45 C. Confidence interval = 7.24 0.89 D. Confidence interval = 7.24 0.25 18. Consider the sets of replicate measurements of Hg ion concentration in a lake water sample: 2.7 ppm 3.0 ppm 2.6 ppm 2.8 ppm 3.2 ppm Calculate the mean and the standard deviation for the data set. A. Mean =2.9 standard deviation= 0.78 B. Mean =2.9 standard deviation= 0.24 C. Mean =2.6 standard deviation= 0.67 D. Mean =2.6 standard deviation= 0.21 19. Estimate the results of the following calculations. Round the result so that it contains only significant figures. The numbers in parentheses are absolute standard deviations. y=3.73( 0.03) + 0.903( 0.001)-7.025( 0.001) A. Result = -2.39 ( 0.01) B. Result = +2.39 ( 0.06) C. Result = +2.39 ( 0.09) D. Result = -2.39 ( 0.03) 20. Estimate the results of the following calculations. Round the result so that it contains only significant figures. The numbers in parentheses are absolute standard deviations. y = 267 ( ± 0.03 ) × 10 14 1.47 ( ± 0.04 ) × 10 16 A. Result=1.82 10 4 ( 0.05 10 4 ) B. Result=1.45 10 4 ( 0.05 10 4 ) C. Result=1.82 10 4 ( 0.02 10 4 ) D. Result=2.32 10 4 ( 0.15 10 4 ) 4